화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.134, 252-260, 2015
Suitability of layered Ti3SiC2 and Zr-3[Al(si)](4)C-6 ceramics as high temperature solar absorbers for solar energy applications
Layered Ti3SiC2 and Zr-3[Al(si)](4)C-6 ceramics were prepared by hot-pressed sintering. The spectrally selective absorption properties of these layered carbides have been investigated and compared with those of TiC and ZrC. It is found that the Ti3SiC2 ceramic exhibits a solar absorbance of 0.70 and a thermal emissivity of 0.19, yielding spectral selectivity (absorbance divide by emissivity) of 3.7, while the spectral selectivity of Zr-3[Al(si)](4)C-6 is 2.8 (0.71/0.25). To evaluate the suitability of these ceramics as high-temperature absorbers for solar radiation, the investigation on the thermal stability and temperature dependent emittance was performed in air. Compared with TiC and ZrC, both Ti3SiC2 and Zr-3[Al(si)](4)C-6 show better thermal stability. Meanwhile, Ti3SiC2 and Zr-3[Al(si)](4)C-6 exhibit a low emissivity in the investigated temperature range, benefiting from their metal-like electrical conductivity. (C) 2014 Elsevier B.V. All rights reserved.