Cu2ZnSnS4 (CZTS) thin films were prepared by sol-gel method and sulfurization process. The effects of the sulfurization temperature on the structural, morphological, compositional, and opto-electrical properties of the CZTS films were investigated. X-ray diffraction and Raman spectroscopy analyses confirmed the formation of CZTS films. With increasing sulfurization temperature, the crystallinity of the films was enhanced, which was accompanied by metallic deficiency, especially tin loss. When the sulfurization temperature was increased from 460 to 540 degrees C, the optical band-gap value decreased from 1.63 to 1.38 eV, while the resistivity and mobility increased from1.415 to 1313 Omega.cm and from 0.372 to 7.231 cm(2)/V.s, respectively. The best CZTS film properties with a bandgap of 1.47 eV, resistivity of 581.5 Omega.cm, carrier concentration of 2.165 x 10(16) cm(-3) and mobility of 1.411 cm(2)/(V.s) were achieved at a sulfurization temperature of 500 degrees C, and make the films suitable as absorbers for solar cells. (C) 2014 Elsevier B.V. All rights reserved.