Worldwide consumption of manganese is increasing, nevertheless huge amounts of manganese from hydrometallurgical processes still end up as waste since the recovery of manganese from multi-metal solutions at low concentrations is not considered feasible. Poor iron control typically prevents the production of high purity manganese. This work studies a number of precipitants in manganese recovery and iron separation from sulfate solutions. The precipitation reagents were compared from the point of view of selectivity and economy. Carbonate precipitation is a fast and effective method for the recovery of manganese from bulk solutions. Subsequent leaching of metal carbonate is also easier and consumes less acid than, for example, hydroxide or sulfide precipitates. In order to avoid gypsum formation, soda ash should be used instead of limestone. It was found that efficient selective iron removal from MnSO(4) solutions is achieved with combined O(2) or air oxidation and CaCO(3) precipitation at pH >5.8 and at a redox potential of >200 mV. Effective mixing and sufficient retention time are essential to make the method technically efficient and economically feasible. (C) 2011 Elsevier Ltd. All rights reserved.