화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.32, No.5, 808-815, May, 2015
DOI10.1007/s11814-014-0279-9  Export Citation
Adsorption breakthrough dynamics of zeolites for ethylene recovery from fluid catalytic cracking fuel-gas
Dooyong Park, Eun-Ji Woo, Ji Won Choi, Hyungwoong Ahn1, and Chang-Ha Lee†
  • Department of Chemical and Biomolecular Engineering, Yonsei University, Seoul 120-749, Korea
  • 1Scottish Carbon Capture and Storage Centre, Institute for Materials and Processes, The University of Edinburgh, UK
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The adsorption dynamics of zeolite 13X, 10X and 5A beds was investigated for recovering ethylene (C2H4) from fluidized catalytic cracking fuel-gas. As a feed gas, a ternary mixture (CH4 : C2H4 : C2H6) and a model FCC fuelgas (CH4 : C2H4 : C2H6 : C3H6 : N2 : H2) were used for breakthrough experiments. In the ternary mixture, the concentration profiles showed similar patterns in all zeolite beds. C2H4 showed higher adsorption affinity than the others in all zeolites and zeolite 5A had the highest adsorption capacity of C2H4. In the six-component mixture, the breakthrough curves in the zeolite 5A bed showed similar patterns to the results of the ternary mixture. Although weak adsorbates could be removed during the adsorption step, CH4 and N2 imparted a steric hindrance to the initial stage of C2H4 adsorption in the zeolite 5A bed. Since vacuum desorption contributed to producing a high purity of C2H4, a pressure vacuum swing adsorption process was recommended to recover C2H4.
Keywords:Zeolite;Adsorption;FCC Fuel-gas;Ethylene;C2H4;PVSA
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