pH 진동계 안에서 pH 감응성 자기진동 IPN 하이드로젤의 합성과 분석

Liping Wang; Jie Ren; Xiaoyan Zhang; Xiaoci Yang; Wu Yang

Polymer(Korea), Vol.39, No.3, 359-364, May, 2015

DOI10.7317/pk.2015.39.3.359 Export Citation

pH 진동계 안에서 pH 감응성 자기진동 IPN 하이드로젤의 합성과 분석

Synthesis and Characterization of pH-sensitive and Self-oscillating IPN Hydrogel in a pH Oscillator

Liping Wang, Jie Ren^†, Xiaoyan Zhang, Xiaoci Yang, and Wu Yang

Chemistry & Chemical Engineering College, Chemistry & Chemical Engineering College, Northwest Normal University, Key Lab of Bioelectrochemtry & Environmental Analysis of Gansu, Lanzhon, 730070, P.R. China

E-mail:

A self-oscillating interpenetrating polymer network (IPN) poly(acrylic acid)/poly(ethylene glycol) (PAA/PEG) hydrogel was prepared by using radical polymerization with a two-step method. The IPN hydrogel was characterized by FTIR spectroscopy and morphological analysis. The results indicated that the chains of PEG and PAA twined to form porous structure which is beneficial to water molecules entering inside of the hydrogel. In addition, the pH-responsive behavior, salt sensitivity, swelling/de-swelling oscillatory behaviors and self-oscillation in a closed pH oscillator were also studied. The results showed that the prepared hydrogel exhibited pH-sensitivity, good swelling/de-swelling reversibility and excellent salt sensitivity. The self-oscillating behavior of swelling/de-swelling for the prepared hydrogel was caused by pH alteration coupled with the external media. This study may create a new possibility as biomaterial including new self-walking actuators and other related devices.

Keywords:PAA/PEG IPN hydrogel;reversibility;self-oscillation;pH-responsiveness

[References]

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Alzari V, Monticelli O, Nuvoli D, Kenny JM, Mariani A, Biomacromolecules, 40, 2672 (2009)
Rapoport N, Prog. Polym. Sci, 32, 962 (2007)
Motornov M, Roiter Y, Tokarev I, Minko S, Prog. Polym. Sci, 35, 174 (2010)
Zhang YX, Wu FP, Li MZ, Wang EJ, Polymer, 46(18), 7695 (2005)
Zhao S, Cao M, Li H, Li L, Xu X, Carbohydr. Res., 345, 425 (2010)
Liu MM, Su HJ, Tan TW, Carbohydr. Polym., 87, 2425 (2012)
Kim SJ, Yoon SG, Lee YM, Kim SI, Sens. Actuators B-Chem., 88, 286 (2003)
Yoshida R, Takahashi T, Yamaguchi T, Ichijo H, J. Am. Chem. Soc., 118(21), 5134 (1996)
Taniguchi H, Suzuki D, Yoshida R, J. Phys. Chem. B, 114(7), 2405 (2010)
Gyorgyi L, Turanyi T, Field RJ, J. Phys. Chem., 94, 7162 (1990)
Field RJ, Noyes RM, J. Am. Chem. Soc., 96, 2001 (1974)
Bilici C, Karayel S, Demir TT, Okay O, J. Appl. Polym. Sci., 118(5), 2981 (2010)
Yoshida R, Adv. Mater., 22(31), 3463 (2010)
Murase Y, Hidaka M, Yoshida R, Sens. Actuators B-Chem., 149, 272 (2010)
Murase Y, Maeda S, Hashimoto S, Yoshida R, Langmuir, 25(1), 483 (2009)
Yoshida R, Uesusuki Y, Biomacromolecules, 6(6), 2923 (2005)
Zhang J, Peppas NA, Macromolecules, 33(1), 102 (2000)
Edblom EC, Luo Y, Orban M, Kustin K, Epstein IR, J. Phys. Chem., 93, 2122 (1989)
Okazaki N, Rabai G, Hanazaki I, J. Phys. Chem. A, 103(50), 10915 (1999)
Dogu Y, Okay O, J. Appl. Polym. Sci., 99(1), 37 (2006)
Tamashiro MN, Levin Y, Barbosa MC, Eur. Phys. J. B, 1, 337 (1998)
Gou BL, Gao QY, Carbohydr. Res., 342, 2416 (2007)

[Referenced By]

[1] Stuart MAC, Huck WTS, Genzer J, Muller M, Ober C, Stamm M, Sukhorukov GB, Szleifer I, Tsukruk VV, Urban M, Winnik F, Zauscher S, Luzinov I, Minko S, Nat. Mater., 9(2), 101 (2010)

[2] Tokarev I, Gopishetty V, Zhou J, Pita M, Motornov M, Katz E, Minko S, Appl. Mater., 3, 532 (2009)

[3] Wang J, Sun DDN, Shin-ya Y, Leong KW, Macromolecules, 37(2), 670 (2004)

[4] Alzari V, Monticelli O, Nuvoli D, Kenny JM, Mariani A, Biomacromolecules, 40, 2672 (2009)

[5] Rapoport N, Prog. Polym. Sci, 32, 962 (2007)

[6] Motornov M, Roiter Y, Tokarev I, Minko S, Prog. Polym. Sci, 35, 174 (2010)

[7] Zhang YX, Wu FP, Li MZ, Wang EJ, Polymer, 46(18), 7695 (2005)

[8] Zhao S, Cao M, Li H, Li L, Xu X, Carbohydr. Res., 345, 425 (2010)

[9] Liu MM, Su HJ, Tan TW, Carbohydr. Polym., 87, 2425 (2012)

[10] Kim SJ, Yoon SG, Lee YM, Kim SI, Sens. Actuators B-Chem., 88, 286 (2003)

[11] Yoshida R, Takahashi T, Yamaguchi T, Ichijo H, J. Am. Chem. Soc., 118(21), 5134 (1996)

[12] Taniguchi H, Suzuki D, Yoshida R, J. Phys. Chem. B, 114(7), 2405 (2010)

[13] Gyorgyi L, Turanyi T, Field RJ, J. Phys. Chem., 94, 7162 (1990)

[14] Field RJ, Noyes RM, J. Am. Chem. Soc., 96, 2001 (1974)

[15] Bilici C, Karayel S, Demir TT, Okay O, J. Appl. Polym. Sci., 118(5), 2981 (2010)

[16] Yoshida R, Adv. Mater., 22(31), 3463 (2010)

[17] Murase Y, Hidaka M, Yoshida R, Sens. Actuators B-Chem., 149, 272 (2010)

[18] Murase Y, Maeda S, Hashimoto S, Yoshida R, Langmuir, 25(1), 483 (2009)

[19] Yoshida R, Uesusuki Y, Biomacromolecules, 6(6), 2923 (2005)

[20] Zhang J, Peppas NA, Macromolecules, 33(1), 102 (2000)

[21] Edblom EC, Luo Y, Orban M, Kustin K, Epstein IR, J. Phys. Chem., 93, 2122 (1989)

[22] Okazaki N, Rabai G, Hanazaki I, J. Phys. Chem. A, 103(50), 10915 (1999)

[23] Dogu Y, Okay O, J. Appl. Polym. Sci., 99(1), 37 (2006)

[24] Tamashiro MN, Levin Y, Barbosa MC, Eur. Phys. J. B, 1, 337 (1998)

[25] Gou BL, Gao QY, Carbohydr. Res., 342, 2416 (2007)