화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.32, No.6, 1081-1093, June, 2015
DOI10.1007/s11814-014-0296-8  Export Citation
Evaluation of biomass component effect on kinetic values for biomass pyrolysis using simplex lattice design
Sasiporn Chayaporn1, Panusit Sungsuk1, Sasithorn Sunphorka1, Prapan Kuchonthara1, 2, Pornpote Piumsomboon1, 2, and Benjapon Chalermsinsuwan1, 2, †
  • 1Fuels Research Center, Department of Chemical Technology, Faculty of Science, Chulalongkorn University, 254 Phayathai Road, Patumwan, Bangkok 10330, Thailand
  • 2Center of Excellence on Petrochemical and Material Technology, Chulalongkorn University, 254 Phayathai Road, Patumwan, Bangkok 10330, Thailand
E-mail:
Abstract.We evaluated the correlation between the biomass constituents and their kinetic values. To simplify the models and indicate the effect of each constituent, pure biomass components and their mixtures were used as biomass model. The experiments were set up based on simplex-lattice design. The pyrolysis of synthesized biomass was performed by non-isothermal thermogravimetric analyzer. Several kinetic models in the literature, including Kissinger-Akahira-Sunose, Ozawa-Flynn-Wall and analytical method were used to determine kinetic values for each experiment. The generated regression models and predicted kinetic values from those methods were compared. The results obtained from analytical model (for n≠1) showed a good agreement (R2>0.95) with those obtained from experiments. This study also provide contour plots for all cases in order to observe the behavior of biomass pyrolysis at different component ratio.
Keywords:Simplex-lattice Design;Biomass;Pyrolysis;Model;Kinetics
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