화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.24, No.11, 573-577, November, 2014
PdOx가 도핑된 나노 기공구조 SiO2/Si 기반의 수소 게터 제작 및 특성평가
Fabrication and Characterization of Hydrogen Getter Based on Palladium Oxide Doped Nanoporous SiO2/Si Substrate
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The existing metal getters are invariably covered with thin oxide layers in air and the native oxide layer must be dissolved into the getter materials for activation. However, high temperature is needed for the activation, which leads to unavoidable deleterious effects on the devices. Therefore, to improve the device efficiency and gas-adsorption properties of the device, it is essential to synthesize the getter with a method that does not require a thermal activation temperature. In this study, getter material was synthesized using palladium oxide (PdOx) which can adsorb H2 gas. To enhance the efficiency of the hydrogen and moisture absorption, a porous layer with a large specific area was fabricated by an etching process and used as supporting substrates. It was confirmed that the moisture-absorption performance of the SiO2/Si was characterized by water vapor volume with relative humidity. The gas-adsorption properties occurred in the absence of the activation process.
  1. Brochure SAES Getters: Customized Solutions for Device Miniaturization, (2007).
  2. Deng G, Zhao X, Wang S, Liu X, Li Z, Jiang L, J. Hydrol. Eng., 38, 13050 (2013)
  3. Avdiaj S, Setina-Batic B, Setina J, Erjavec B, Mater. Technol., 45(1), 33 (2011)
  4. Boffito C, Ferrario B, della Porta P, Rosai L, J. Vac. Sci. Technol., 18(3), 1117 (1981)
  5. Chiggiato P, Pinto PC, Thin Solid Films, 515(2), 382 (2006)
  6. Park JS, Suh CY, Kim WB, Korean J. Mater. Res., 15(12), 802 (2005)
  7. Choi HY, Kim MS, Kim GS, Cho MY, Jeon SM, Yim KG, Lee DY, Kim JS, Kim JS, Leem JY, J. Korean Inst. Surf. Eng., 43(3), 121 (2010)
  8. Imai S, Takahashi M, Matsuba K, Asuha, Ishikawa Y, Kobayashi H, Acta Phys. Slovaca, 55(3), 305 (2005)
  9. Smith HM, Schicker JR, Patent, US5888925 A (1999).
  10. Li WC, Balk TJ, Materials, 2, 2496 (2009)
  11. Luongo K, Sine A, Bhansali S, Sens. Actuators B-Chem., 111-112, 125 (2005)
  12. Karagounis VA, Liu CC, Neuman MR, Romankiw LT, Leary PA, Cuomo JJ, IEEE Trans. Biomed. Eng., 33, 113 (1986)
  13. Zhao J, Wang W, Liu Y, Ma J, Li X, Du Y, Lu G, Sens. Actuators B-Chem., 160, 604 (2011)
  14. Lee YT, Kim YJ, Lee JM, Joe JH, Lee WY, J. Korean Inst. Met. Mater., 48(4), 347 (2010)
  15. Liu QS, Gath KK, Bauer JC, Schaak RE, Lunsford JH, Catal. Lett., 132(3-4), 342 (2009)
  16. Exley J, Part I: Characterization of Supported Palladium, Hydrogen Sorption, 19 1 4-5 (2008) from http://www.micromeritics.com