화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.32, No.7, 1361-1368, July, 2015
DOI10.1007/s11814-014-0332-8  Export Citation
Application of modified Tao-Mason equation of state to refrigerant mixtures
Masoumeh Kiani†, Mohammad Mehdi Papari1, Zahra Nowruzian2, and Jalil Moghadasi2
  • Department of Chemistry, Payame Noor University, P. O. Box 19395-3697, Tehran, Iran
  • 1Department of Chemistry, Shiraz University of Technology, Shiraz 71555-313, Iran
  • 2Department of Chemistry, Shiraz University, Shiraz, Iran, Korea
E-mail:
In our previous work, we modified the Tao-Mason EOS [1] to predict the volumetric properties of pure refrigerants [2]. In the present study, we have successfully extended the modified Tao-Mason EOS to refrigerant mixtures. The second virial coefficient, B2(T), and the temperature-dependent correction factor α(T) and van der Waals co-volume b(T) were calculated from a two-parameter corresponding-states correlation along with the enthalpy of vaporization and the molar density, both at the normal boiling point. Then the cross parameters B12(T), α12(T), and b12(T), were determined with the help of simple combining rules. The constructed Tao-Mason EOS was employed to predict the densities and vapor pressures of several HFC, hydrocarbons and HFO mixtures. The calculated results were compared with literature data. The overall agreement between our results and literature values is remarkable.
Keywords:Refrigerant;Mixtures;Equation of State;Volumetric Properties;Corresponding States Principle
  1. Tao FM, Mason EA, J. Chem. Phys., 100(12), 9075 (1994)
  2. Papari MM, Nejabat R, Moghadasi J, Campo A, Int. J. Refrig., 34, 268 (2011)
  3. Madani H, Coquelet C, Richon D, Energy Procedia, 18, 21 (2012)
  4. Madani H, Valtz A, Coquelet C, Meniai AH, Richon D, Fluid Phase Equilib., 268(1-2), 68 (2008)
  5. Chen Q, Hong RH, Chen GM, Fluid Phase Equilib., 269(1-2), 113 (2008)
  6. Mohanraj M, Jayaraj S, Muraleedharan C, Int. J. Greenhouse Gas Control, 3, 108 (2009)
  7. Fukuta M, Ito M, Yanagisawa T, Ogi Y, Int. J. Refrig., 33, 390 (2010)
  8. Papari MM, Razavizadeh A, Mokhberi F, Boushehri A, Ind. Eng. Chem. Res., 42(16), 3802 (2003)
  9. Sharafi Z, Boushehri A, Int. J. Thermophys., 26, 785 (2006)
  10. Feroiu V, Geana D, Fluid Phase Equilib., 207(1-2), 283 (2003)
  11. Goharshadi EK, Moosavi M, Thermochim. Acta, 447(1), 64 (2006)
  12. Richter M, McLinden MO, Lemmon EW, J. Chem. Eng. Data, 56(7), 3254 (2011)
  13. Yamaya K, Matsuguchi A, Kagawa N, Koyama S, J. Chem. Eng. Data, 56(4), 1535 (2011)
  14. Akasaka R, Int. J. Thermophys., 32, 1125 (2011)
  15. Akasaka R, Fluid Phase Equilib., 358, 98 (2013)
  16. Akasaka R, Tanakaand K, Higashi Y, Int. J. Refrig., 33, 52 (2010)
  17. Akasaka R, Int. J. Refrig., 33, 907 (2010)
  18. Brown JS, Int. J. Refrig., 30, 1319 (2007)
  19. Di Nicola C, Di Nicola G, Pacetti M, Polonara F, Santori G, J. Chem. Eng. Data, 55(9), 3302 (2010)
  20. Tanaka K, Takahashi G, Higashi Y, J. Chem. Eng. Data, 55(6), 2169 (2010)
  21. Kamiaka T, Dangand C, Hihara E, Int. J. Refrig., 36, 965 (2013)
  22. Li MX, Dang CB, Hihara E, Int. J. Heat Mass Transf., 55(13-14), 3437 (2012)
  23. Brown JS, Zilio C, Cavallini A, Proc. 3rd IIR Conf. on Thermophys Props. & Transport Processes of Refrigs, Boulder, Colorado(2009).
  24. Perkins RA, Huber ML, J. Chem. Eng. Data, 56(12), 4868 (2011)
  25. Haghighi B, Heidari F, Haghighi B, Papari MM, Haghighi B, Int. J. Air-Cond. Refrig., 19, 45 (2011)
  26. Moghadasi J, Mohammad-Aghaie D, Papari MM, Ind. Eng. Chem. Res., 45(26), 9211 (2006)
  27. Moghadasi J, Papari MM, Mohammad-Aghaie D, Campo A, Bull. Chem. Soc. Jpn., 81, 220 (2008)
  28. Ihm G, Song Y, Mason EA, J. Chem. Phys., 94, 3839 (1991)
  29. Eslami H, Mehdipour N, Boushehri A, Int. J. Refrig., 29, 150 (2006)
  30. Yousefi F, Moghadasi J, Papari MM, Campo A, Ind. Eng. Chem. Res., 48(10), 5079 (2009)
  31. Sheikh S, Papari MM, Boushehri A, Ind. Eng. Chem. Res., 41(13), 3274 (2002)
  32. Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
  33. Tao FM, Mason EA, Int. J. Thermophys., 13, 1053 (1992)
  34. Boushehri A, Mason EA, Int. J. Thermophys., 14, 685 (1993)
  35. Ghatee MH, Boushehri A, Int. J. Thermophys., 17, 945 (1996)
  36. Mehdipourand N, Boushehri A, Int. J. Thermophys., 19, 331 (1998)
  37. Eslami H, Int. J. Thermophys., 22, 1781 (2001)
  38. Papari MM, Kiani M, Behjatmanesh-Ardakani R, Moghadasi J, Campo A, J. Mol. Liq., 161, 148 (2011)
  39. Papari MM, Behjatmanesh-Ardakani R, Kiani M, Moghadasi J, Campo A, Colloid Polym. Sci., 289, 1081 (2011)
  40. Ihm G, Song Y, Mason EA, Mol. Phys., 75, 897 (1992)
  41. Eslami H, Papari MM, Boushehri J, J. Phys. Soc. Jpn., 70, 1015 (2001)
  42. Mohr PJ, Taylor BN, Newell DB, Rev. Mod. Phys., 84, 1527 (2012)
  43. Tsonopoulos C, AIChE J., 20, 263 (1974)
  44. Pannock J, Didion DA, The Performance of Chlorine-Free Binary Zeotropic Refrigerant Mixtures in a Heat Pump, Building and Fire Research Laboratory National Institute of Standards and Technology Gaithersburg, Maryland (1991).
  45. Weber LA, Defibaugh DR, Int. J. Thermophys., 15, 863 (1994)
  46. Weber F, Fluid Phase Equilib., 174(1-2), 165 (2000)
  47. Zhang HL, Sato H, Watanabe K, J. Chem. Eng. Data, 41(6), 1401 (1996)
  48. Kiyoura H, Takebe J, Uchida H, Sato H, Watanabe K, J. Chem. Eng. Data, 41(6), 1409 (1996)
  49. Zhang HL, Tada S, Sato H, Watanabe K, Fluid Phase Equilib., 150-151, 333 (1998)
  50. Widiatmo JV, Fujimine T, Sato H, Watanabe K, J. Chem. Eng. Data, 42(2), 270 (1997)
  51. Meng L, Duan YY, Chen Q, J. Chem. Eng. Data, 49(6), 1821 (2004)
  52. Yokoyama C, Nishino T, Takahashi M, Int. J. Thermophys., 25, 71 (2004)
  53. Sato T, Kiyoura H, Sato H, Watanabe K, J. Chem. Eng. Data, 39(4), 855 (1994)
  54. Feng XJ, Duan YY, Dong W, J. Chem. Eng. Data, 52(4), 1354 (2007)
  55. Raabe G, J. Chem. Eng. Data, 58(6), 1867 (2013)
  56. IUPAC Ionic Liquids Database (IL Thermo), NIST Standard Reference Database#147, http://ilthermo.boulder.nist.gov/ILThermo/mainmenu.uix, Access January (2008).
  57. Higashi Y, Tanaka K, Ichikawa T, J. Chem. Eng. Data, 55(4), 1594 (2010)
  58. McLinden MO, Thol M, Lemmon EW, Thermodynamic Properties of trans-1,3,3,3-tetrafluoropropene [R1234ze(E)]:Measurements of Density and Vapor Pressure and a Comprehensive Equation of State, International Refrigeration and Air Conditioning Conference at Purdue (2010).
  59. Di Nicola G, Passerini G, Polonara F, Stryjek R, Fluid Phase Equilib., 360, 124 (2013)
  60. Kayukawa Y, Hasumoto M, Kano Y, Watanabe K, J. Chem. Eng. Data, 50(2), 565 (2005)