Carbon dioxide capture on primary amine groups entrapped in activated carbon at low temperatures

Young-Chul Lee; Sang Moon Lee; Won G. Hong; Yun Suk Huh; So Young Park; Soon Chang Lee; Jouhahn Lee; Jin Bae Lee; Hyun Uk Lee; Hae Jin Kim

Journal of Industrial and Engineering Chemistry, Vol.23, 16-20, March, 2015

DOI10.1016/j.jiec.2014.08.020 Export Citation

Carbon dioxide capture on primary amine groups entrapped in activated carbon at low temperatures

Young-Chul Lee, Sang Moon Lee¹, Won G. Hong¹, Yun Suk Huh², So Young Park¹, Soon Chang Lee³, Jouhahn Lee¹, Jin Bae Lee¹, Hyun Uk Lee^{1, †}, and Hae Jin Kim^{1, †}

Department of BioNano Technology, Gachon University, 1342 Seongnamdaero, Sujeong-gu, Seongnam-si, Gyeonggi-do 461-701, Republic of Korea
¹Division of Materials Science, Korea Basic Science Institute (KBSI), Daejeon 305-806, Republic of Korea
²Department of Biological Engineering, College of Engineering, Inha University, Incheon 402-751, Republic of Korea
³Department of Applied Chemistry and Biological Engineering, Chungnam National University, Daejeon 305-764, Republic of Korea

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For purposes of selective CO2 uptake under ambient conditions, a few number of primary amine groups are selected, including aminoclay (H2N-CL), 3-aminopropyltriethoxysilane (APTES), and dopamine hydrochloride (DA). Coatings of both H2N-CL into activated carbon (AC) show enhanced CO2 adsorption capacity at 273 and 298 K and 1 atm, resulting in 3.069/1.950 mmol/g, compared to 2.872/1.824 mmol/g of pristine AC. However, APTES and DA coated AC at 273 and 298 K and 1 atm are reduced to 2.433/1.762 and 0.429/0.389 mmol/g. Particularly, the coating of H2N-CL nanoparticles into AC exhibits enhanced selectivity of 8.8/18.7, compared to 7.6/15.9 in pristine AC for CO2/N2 at 273 and 298 K at 1 atm.

Keywords:Aminoclay;3-Aminopropyltriethoxysilane;Dopamine;Activated carbon;Carbon dioxide

[References]

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Garcia-Abuin A, Gomez-Diaz D, Navaza JM, J. Ind. Eng. Chem., 20(4), 2272 (2014)
Lee JM, Min YJ, Lee KB, Jeon SG, Na JG, Ryu HJ, Langmuir, 26(24), 18788 (2010)
Chen C, Yang ST, Ahn WS, Ryoo R, Chem. Commun., 24, 3627 (2009)
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Alesi WR, Gray M, Kitchin JR, ChemSusChem, 3, 948 (2010)
Caglayan BS, Aksoylu AE, J. Hazard. Mater., 252-253, 19 (2013)
Lee YC, Jin ES, Jung SW, Kim YM, Chang KS, Yang JW, Kim SW, Kim YO, Shin HJ, Sci. Rep., 3(1-8), 1292 (2013)
Farooq W, Lee YC, Han JI, Darpito CH, Choi M, Yang JW, Green Chem., 15, 749 (2013)
Hong SM, Kim SH, Lee KB, Energy Fuels, 27(6), 3358 (2013)
Ko JW, Kim SW, Hong J, Ryu J, Kang K, Park CB, Green Chem., 14, 2391 (2012)
Moura KO, Pastore HO, Environ. Sci. Technol., 47, 12201 (2013)
Song D, Lee YC, Park SB, Han JI, RSC Adv., 4, 4037 (2014)
Wang JT, Wang M, Zhao BB, Qiao WM, Long DH, Ling LC, Ind. Eng. Chem. Res., 52(15), 5437 (2013)
Yang H, Gong M, Chen Y, J. Nat. Gas Chem., 20, 460 (2011)
Zhang ZJ, Xu MY, Wang HH, Li Z, Chem. Eng. J., 160(2), 571 (2010)
Zhu LJ, Lu YL, Wang YQ, Zhang LQ, Wang WC, Appl. Surf. Sci., 258(14), 5387 (2012)
Patel HA, Je SH, Park J, Chen DP, Jung Y, Yavuz CT, Coskun A, Nat. Commun., 4(1-8), 1357 (2013)
Britt D, Furukawa H, Wang B, Glover TG, Yaghi OM, Proc. Natl. Acad. Sci. U. S. A., 106, 20637 (2009)
Dillon EP, Crouse CA, Barron AR, ACS Nano, 2, 156 (2008)
Lee YC, Yang JW, J. Ind. Eng. Chem., 18(3), 1178 (2012)

[Referenced By]

[1] Choi S, Drese JH, Jones CW, ChemSusChem, 2, 796 (2009)

[2] D’Alessandro DM, Smit B, Long JR, Angew. Chem.-Int. Edit., 49, 6058 (2010)

[3] Wang Q, Luo J, Zhong Z, Borgna A, Energ. Environ. Sci., 4, 42 (2011)

[4] Choi BG, Park HS, Kim GH, Jung YM, Yi KB, Kim JN, Hong WH, J. Ind. Eng. Chem., 18(1), 98 (2012)

[5] Sistla YS, Khanna A, J. Ind. Eng. Chem., 20(4), 2497 (2014)

[6] Garcia-Abuin A, Gomez-Diaz D, Navaza JM, J. Ind. Eng. Chem., 20(4), 2272 (2014)

[7] Lee JM, Min YJ, Lee KB, Jeon SG, Na JG, Ryu HJ, Langmuir, 26(24), 18788 (2010)

[8] Chen C, Yang ST, Ahn WS, Ryoo R, Chem. Commun., 24, 3627 (2009)

[9] Yue MB, Sun LB, Cao Y, Wang ZJ, Wang Y, Yu Q, Zhu JH, Microporous Mesoporous Mater., 114, 74 (2008)

[10] Choi S, Drese JH, Eisenberger PM, Jones CW, Environ. Sci. Technol., 45, 2420 (2011)

[11] Liu L, Deng QF, Hou XX, Yuan ZY, J. Mater. Chem., 22, 15540 (2012)

[12] Alesi WR, Gray M, Kitchin JR, ChemSusChem, 3, 948 (2010)

[13] Caglayan BS, Aksoylu AE, J. Hazard. Mater., 252-253, 19 (2013)

[14] Lee YC, Jin ES, Jung SW, Kim YM, Chang KS, Yang JW, Kim SW, Kim YO, Shin HJ, Sci. Rep., 3(1-8), 1292 (2013)

[15] Farooq W, Lee YC, Han JI, Darpito CH, Choi M, Yang JW, Green Chem., 15, 749 (2013)

[16] Hong SM, Kim SH, Lee KB, Energy Fuels, 27(6), 3358 (2013)

[17] Ko JW, Kim SW, Hong J, Ryu J, Kang K, Park CB, Green Chem., 14, 2391 (2012)

[18] Moura KO, Pastore HO, Environ. Sci. Technol., 47, 12201 (2013)

[19] Song D, Lee YC, Park SB, Han JI, RSC Adv., 4, 4037 (2014)

[20] Wang JT, Wang M, Zhao BB, Qiao WM, Long DH, Ling LC, Ind. Eng. Chem. Res., 52(15), 5437 (2013)

[21] Yang H, Gong M, Chen Y, J. Nat. Gas Chem., 20, 460 (2011)

[22] Zhang ZJ, Xu MY, Wang HH, Li Z, Chem. Eng. J., 160(2), 571 (2010)

[23] Zhu LJ, Lu YL, Wang YQ, Zhang LQ, Wang WC, Appl. Surf. Sci., 258(14), 5387 (2012)

[24] Patel HA, Je SH, Park J, Chen DP, Jung Y, Yavuz CT, Coskun A, Nat. Commun., 4(1-8), 1357 (2013)

[25] Britt D, Furukawa H, Wang B, Glover TG, Yaghi OM, Proc. Natl. Acad. Sci. U. S. A., 106, 20637 (2009)

[26] Dillon EP, Crouse CA, Barron AR, ACS Nano, 2, 156 (2008)

[27] Lee YC, Yang JW, J. Ind. Eng. Chem., 18(3), 1178 (2012)