Journal of Industrial and Engineering Chemistry, Vol.23, 72-78, March, 2015
Structural characterization of the solid residue produced by hydrothermal treatment of sunflower stalks and subsequent enzymatic hydrolysis
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This study was to structurally characterize solid residues obtained from sunflower stalks hydrothermally treated at 180 and 200 °C for 30 min, followed by enzymatic hydrolysis. Recovered solid residue were 25.3% and 24.1% of fresh biomass, respectively. Each ethanol soluble fraction could be obtained up to 30% of the solid residue. The fraction from the solid residue at 200 °C was composed of smaller-sized lignin macromolecules with higher phenolic hydroxyl group, but lower aliphatic hydroxyl due to enhanced cleavage reactions related to side chain and aryl ether linkages of lignin, compared to that of the solid residue at 180 °C.
Keywords:Sunflower stalks;Hydrothermal treatment;Solid residue;Lignin-enriched fraction;Lignin valorization
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