화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.23, 100-108, March, 2015
DOI10.1016/j.jiec.2014.07.047  Export Citation
Dicationic poly(4-vinyl pyridinium) ionic liquid capsules as template for Co nanoparticle preparation and H2 production from hydrolysis of NaBH4
Nurettin Sahiner1, 2, †, Alper O. Yasar2, 3, and Nahit Aktas4
  • 1Nanoscience and Technology Research and Application Center (NANORAC), Faculty of Sciences and Arts, Canakkale, Turkey
  • 2Chemistry Department, Terzioglu Campus, Canakkale 17100, Turkey
  • 3, Turkey
  • 4Engineering Faculty, Chemical Engineering Department, Yuzuncu Yil University, Van, 65080, Turkey
E-mail:
Poly(4-vinyl pyridine)-silica (p(4-VP)-silica) composites were synthesized via micro emulsion polymerization, and the capsule of p(4-vinyl pyridine), as cap-p(4-VP), was prepared by removing the core silica from p(4-VP)-silica composites by HF treatment. Dicationic particles in the form of cap-poly(4-vinyl pyridine)++-1,4-butane (cap-p(4-VP)++-C4), capsule-poly(4-vinyl pyridine)++-1,6-hexane (cap-p(4-VP)++-C6), and capsule-poly(4-vinyl pyridine)++-1,8-octane (cap-p(4-VP)++-C8) were prepared by modifying cap-p(4-VP) particles with corresponding dibromo alkanes. Then, polymer?metal composites were also prepared from cap-p(4-VP) and dicationic cap-p(4-VP) particles by loading CoCl2 from ethanol and the obtained composites were used in H2 generation from hydrolysis of NaBH4, and The Ea for the composite catalyst was calculated as 56.53 kJ/mol.
Keywords:Capsule p(4-VP);Dicationic particle;Hydrogen production;Microgel;Nanogel
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