화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.23, 119-127, March, 2015
DOI10.1016/j.jiec.2014.08.002  Export Citation
Platinum recovery from model media and a Pt-Sn/alumina spent catalyst extract using corn husk-based adsorbent
Z. Tavassolirizi, K. Shams†, and M.R. Omidkhah1
  • Department of Chemical Engineering, Isfahan University of Technology, Isfahan 8415683111, Iran
  • 1Department of Chemical Engineering, Tarbiat Modares University, Tehran, Iran
E-mail:
Preparation of corn husk-based adsorbent for platinum recovery is studied. The adsorbents are prepared and characterized, and the adsorption of platinum onto the adsorbents is examined. Results indicate that hydroxyl and amine groups are responsible for adsorption of platinum onto the adsorbents. Immobilized amine enhances the adsorption and aluminates interfere in adsorption of platinum ions. The adsorption capacity of the adsorbent with immobilized amine for model media and intact solution is 38.5 and 16.2 mg Pt/(g adsorbent), respectively. Structural changes of the treated corn husk is explained by Mannich mechanisms. The kinetics of adsorption of Pt follows a pseudo-second-order model.
Keywords:Spent catalyst;Corn husk;Adsorbent;Precious metals group;Platinum recovery;Adsorption
  1. Angelidis TN, Koutlemani M, Poulios I, Appl. Catal. B: Environ., 16(4), 347 (1998)
  2. Angelidis TN, Rosopoulou D, Tzitzios V, Ind. Eng. Chem. Res., 38(5), 1830 (1999)
  3. Barakat MA, Mahmoud MHH, Hydrometallurgy, 72, 179 (2004)
  4. Benson M, Bennett CR, Harry JE, Patel MK, Cross M, Resour. Conserv. Recycl., 31, 1 (2000)
  5. Cui JR, Zhang LF, J. Hazard. Mater., 158(2-3), 228 (2008)
  6. Faisa M, Atsuta Y, Daimon H, Fujie K, Asia Pac. J. Chem. Eng., 3, 364 (2008)
  7. Godlewska-Zylkiewicz B, Lesniewska B, Gasiewska U, Hulanicki A, Anal. Lett., 33, 2805 (2000)
  8. Hassan A, Richter S, Chem. Eng. Technol., 25(12), 1141 (2002)
  9. Kim B, Lee J, Seo SP, Park YK, Sohn HY, Pyrometall. Fund., 55 (2004)
  10. Kramer J, Driessen WL, Koch KR, Reedijk J, Hydrometallurgy, 64, 59 (2002)
  11. Shams K, Beiggy MR, Shirazi AG, Appl. Catal. A: Gen., 258(2), 227 (2004)
  12. Shams K, Goodarzi F, J. Hazard. Mater., 131(1-3), 229 (2006)
  13. Yoo JS, Catal. Today, 44(1-4), 27 (1998)
  14. Greenwood NN, Earnshaw A, Chemistry of the Elements, 2nd ed., Butterworth-Heinemann, UK, 1997.
  15. Baghalha M, Khosravian GH, Mortaheb HM, Hydrometallurgy, 95, 247 (2009)
  16. Chen J, Huang K, Hydrometallurgy, 82, 164 (2006)
  17. Jafarifara D, Daryanavard MR, Sheibani S, Hydrometallurgy, 78, 166 (2005)
  18. Kayanuma Y, Okabe TH, Maeda M, Metall. Mater. Trans. B-Proc. Metall. Mater. Proc. Sci., 35, 817 (2004)
  19. Mahmoud M, Precious Metals: Aqueous, 37 (2003)
  20. Pinheiro A, Lima TS, Campos PC, Afonso JC, Hydrometallurgy, 74, 77 (2004)
  21. Zanjani A, Baghalha M, Hydrometallurgy, 97, 119 (2009)
  22. Chassarya P, Vincenta T, Marcano JS, Macaskiec LE, Guibal E, Hydrometallurgy, 76, 131 (2005)
  23. Coxa M, Pichuginb AA, El-Shafeyc EI, Appletona Q, Hydrometallurgy, 78, 137 (2005)
  24. Fujiwara K, Ramesh A, Maki T, Hasegawa H, Ueda K, J. Hazard. Mater., 146(1-2), 39 (2007)
  25. Goto, in: Proceedings of European Congress of Chemical Engineering (ECCE-6), 2007.
  26. Guibal E, Sweeney NVO, Zikan MC, Vincent T, Tobin JM, Int. J. Biol. Macromol., 28, 401 (2001)
  27. Jermakowicz-Bartkowiak D, Kolarz BN, Serwin A, React. Funct. Polym., 65(1-2), 135 (2005)
  28. Julsing HG, McCrindle RI, J. Chem. Technol. Biotechnol., 76(4), 349 (2001)
  29. Kasaini H, Mbaya RK, Hydrometallurgy, 97, 111 (2009)
  30. Kavakli C, Malci S, Tuncel SA, Salih B, React. Funct. Polym., 66(2), 275 (2006)
  31. Kramer J, Dhladhia NE, Koch KR, Sep. Purif. Technol., 49(2), 181 (2006)
  32. Lee JY, Kumar JR, Kim JS, Park HK, Yoon HS, J. Hazard. Mater., 168(1), 424 (2009)
  33. Mack C, Wilhelmi B, Duncan JR, Burgess JE, Biotechnol. Adv., 25, 264 (2007)
  34. Matjie RH, Scurrell MS, Bunt J, Miner. Eng., 18(8), 801 (2005)
  35. Pan L, Zhang ZD, Miner. Eng., 22(15), 1271 (2009)
  36. Ramesh A, Hasegawa H, Sugimoto W, Maki T, Ueda K, Bioresour. Technol., 99(9), 3801 (2008)
  37. Rane MV, Venugopal V, Hydrometallurgy, 84, 54 (2006)
  38. Vassileva P, Tzvetkova P, Lakov L, Peshe O, J. Porous Mat., 15, 593 (2008)
  39. Zhou LM, Liu JH, Liu ZR, J. Hazard. Mater., 172(1), 439 (2009)
  40. Amarasinghe BMWPK, Williams RA, Chem. Eng. J., 132(1-3), 299 (2007)
  41. Farinella NV, Matos GD, Lehmann EL, Arruda MAZ, J. Hazard. Mater., 154(1-3), 1007 (2008)
  42. Guibal E, Sep. Purif. Technol., 38(1), 43 (2004)
  43. Ma HW, Liao XP, Liu X, Shi B, J. Membr. Sci., 278(1-2), 373 (2006)
  44. Mack CL, Wilhelmi B, Duncan JR, Burgess JE, Miner. Eng., 21(1), 31 (2008)
  45. Parajuli D, Adhikari CR, Kawakita H, Kajiyama K, Ohto K, Inoue K, React. Funct. Polym., 68(8), 1194 (2008)
  46. Parajuli D, Inoue K, Kawakita H, Ohto K, Harada H, Funaoka M, Miner. Eng., 21(1), 61 (2008)
  47. Parajuli D, Adhikari CR, Kawakita H, Yamada S, Ohto K, Inoue K, Bioresour. Technol., 100(2), 1000 (2009)
  48. Xiong Y, Adhikari CR, Kawakita H, Ohto K, Inoue K, Harada H, Bioresour. Technol., 100(18), 4083 (2009)
  49. http://www.geohive.com/charts/ag_maize.aspx (accessed March 2013).
  50. http://faostat.fao.org/site/567/DesktopDefault.aspxPageID=567#ancor(accessed 12.12.13).
  51. http://www.pioneer.com/. . ./2010_managing_corn_residue.pdf (accessed 20.03.13).
  52. http://online.osu.edu/agf-fact/0003.html (accessed 20.01.14).
  53. http://keshavarsee.ir/archives/80 (accessed 11.04.13).
  54. Hang YD, Woodams EE, LWT - Food Sci. Technol., 33, 520 (2000)
  55. Mahalaxmi Y, Sathish T, Rao CS, Prakasham RS, Process Biochem., 45, 47 (2010)
  56. Norashikin MZ, Ibrahim MZ, World Acad. Sci. Eng. Technol., 58, 176 (2009)
  57. Asadi F, Shariatmadari H, Mirghaffari N, J. Hazard. Mater., 154(1-3), 451 (2008)
  58. Rao MM, Ramana DK, Seshaiah K, Wang MC, Chien SWC, J. Hazard. Mater., 166(2-3), 1006 (2009)
  59. Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
  60. Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
  61. Weber WJM, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civil Eng., 31 (1963)
  62. Boyd GE, Adamson AW, Myers LS, J. Am. Chem. Soc., 67, 2836 (1949)
  63. Lagergren S, Kungl. Svenska Vetenskapsakadomiens Handliger, 24, 1 (1898)
  64. Smith MB, Mach J, March’s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 6th ed., John Wiley and Sons, New Jersey, 2007.
  65. Carey FA, Sundberg RJ, Advanced Organic Chemistry. Part A: Structure and Mechanisms, Plenum Publishers, New York, 2000.