Preconcentration-separation of germanium at ultra trace levels on polysulfone membrane filter and its determination by spectrophotometry

Mustafa Soylak; Sevtap Yigit

Journal of Industrial and Engineering Chemistry, Vol.24, 322-325, April, 2015

DOI10.1016/j.jiec.2014.10.003 Export Citation

Preconcentration-separation of germanium at ultra trace levels on polysulfone membrane filter and its determination by spectrophotometry

Mustafa Soylak, and Sevtap Yigit^†

Department of Chemistry, Erciyes University, Fen Fakultesi, 38039 Kayseri, Turkey

E-mail:

A separation-preconcentration procedure for germanium has been presented. The optimum conditions including pH, sample volume, sample-eluent flow rates, sample and matrix effects for adsorption of germanium(IV) on polysulfone membrane filter were investigated prior to spectrophotometric determination of germanium as Ge(IV)-9-phenyl-3-fluorone complex. Ge(IV) was adsorbed on membrane at pH 4.0 and was eluted from membrane with phosphoric acid. The accuracy was checked by determination of germanium content of GBW 07402 soil certified reference material. The detection and quantification limits were found as 2.1 and 7.0 ng/L, respectively. The method was applied for determination of germanium in soil and water samples.

Keywords:Polysulfone membrane filter;Germanium;UV-vis spectrophotometer;Preconcentration

[References]

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Moskalyk RR, Miner. Eng., 17(3), 393 (2004)
Zou BD, Aodeng GW, Shang HS, Qi L, Spectrosc. Spectr. Anal., 25, 1496 (2005)
Sabarudin A, Umemura T, Motomizu S, Microchem J., 99, 34 (2011)
Jianbo S, Zhiyong S, Chunhua T, Quan T, Zexiang C, Talanta, 56, 711 (2002)
Boyukbayram AE, Volkan M, Spectroc. Acta Pt. B-Atom. Spectr., 55B, 1073 (2000)
Goa H, Liu W, Bull. Korean Chem. Soc., 21, 1090 (2000)
Virolainen S, Heinonen JI, Paatero E, Sep. Purif. Technol., 104, 193 (2013)
Chen Y, Zhu R, Qiang H, Ji F, Gu X, Microchem J., 64, 93 (2000)
Zaijun L, Jiaomai P, Jan T, Anal. Chim. Acta, 445, 153 (2001)
McMahon M, Regan F, Hughes H, Food Chem., 97, 411 (2006)
Zaijun L, Jian T, Huizhen L, Xia Z, Rui Y, J. Food Compos. Anal., 20, 1 (2007)
Xia Z, Zaijun L, Rui Y, Huizhen L, Anal. Lett., 39, 863 (2006)
Zaijun L, Xia Z, Huizhen L, Rui Y, Commun. Soil Sci. Plant Anal., 39, 461 (2008)
Sargar BM, Anuse MA, J. Anal. Chem., 60, 404 (2005)
Shida J, Takahashi Y, Ojima K, Matsuo T, Bunseki Kagaku, 33, 143 (1984)
Kan M, Nasu T, Taga M, Anal. Sci., 5, 707 (1989)
Soylak M, Unsal YE, Kızıl N, Aydin A, Food Chem. Toxicol., 48, 517 (2010)
Gu X, Zhou T, Anal. Lett., 29, 463 (1996)
Soylak M, Erdogan ND, Elci L, J. Chin. Chem. Soc., 51, 703 (2004)
Goto K, Taguchi S, Anal. Sci., 9, 1 (1993)
Divrikli U, Soylak M, Dogan M, Chem. Anal., 45, 257 (2000)
Nakano M, Sekiguchi C, Wakabayashi H, Shimada K, Bunseki Kagaku, 33, 188 (1983)
Soylak M, Sahin U, Elci L, Anal. Acta Chim., 322, 111 (1996)
Zhang PF, Gao HW, Shen NK, Asian J. Chem., 10, 767 (1998)
Ueno K, Imamura T, Cheng KL, Handbook of Organic Analytical Reagents, 2nd edition, 1999, pp. 39-357.
Aydin FA, Soylak M, Talanta, 73, 134 (2007)
Soylak M, Unsal YE, Tuzen M, Yilmaz E, Food Chem. Toxicol., 49, 1796 (2011)
Tuzen M, Soylak M, Elci L, Dogan M, Anal. Lett., 37, 1185 (2004)
Mahmudov KT, Aliyeva RA, Hamidov SZ, Chyragov FM, Mardanova SR, Kopylovich MN, Pombeiro AJL, Am. J. Anal. Chem., 3, 790 (2012)
Duran C, Ozdes D, Bulut VN, Tufekci M, Soylak M, J. AOAC Int., 94, 286 (2011)
Soylak M, Divrikli U, Elci L, Dogan M, Kuwait J. Sci. Eng., 25, 389 (1998)
Shanbhag B, Gosalia R, Asian J. Chem., 20, 2633 (2008)
Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, Desalination, 281, 226 (2011)
Karve M, Rajgor RV, Sep. Sci. Technol., 42(10), 2255 (2007)
Soylak M, Unsal YE, Tuzen M, Food Chem. Toxicol., 49, 1183 (2011)
Soylak M, Elci L, Dogan M, Kuwait J. Sci. Eng., 24, 87 (1997)
Zeinali N, Ghaedi M, Shafie G, J. Ind. Eng. Chem., 20(5), 3550 (2014)
Ghaedi M, Parham H, Moghadam M, Mortazavi K, Soylak M, Ann. Chim., 96, 689 (2006)
Samaddar P, Sen K, J. Ind. Eng. Chem., 20(4), 1209 (2014)
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Kumbasar RA, J. Ind. Eng. Chem., 18(6), 2076 (2012)
Soylak M, Asian J. Chem., 15, 1780 (2003)
Karadas CD, Kara Instrum. Sci. Technol., 42, 548 (2014)
Ueda J, Kitadani T, Anal. Sci., 5, 181 (1989)

[Referenced By]

[1] Holl R, Kling M, Schroll E, Ore Geol. Rev., 30, 145 (2007)

[2] Moskalyk RR, Miner. Eng., 17(3), 393 (2004)

[3] Zou BD, Aodeng GW, Shang HS, Qi L, Spectrosc. Spectr. Anal., 25, 1496 (2005)

[4] Sabarudin A, Umemura T, Motomizu S, Microchem J., 99, 34 (2011)

[5] Jianbo S, Zhiyong S, Chunhua T, Quan T, Zexiang C, Talanta, 56, 711 (2002)

[6] Boyukbayram AE, Volkan M, Spectroc. Acta Pt. B-Atom. Spectr., 55B, 1073 (2000)

[7] Goa H, Liu W, Bull. Korean Chem. Soc., 21, 1090 (2000)

[8] Virolainen S, Heinonen JI, Paatero E, Sep. Purif. Technol., 104, 193 (2013)

[9] Chen Y, Zhu R, Qiang H, Ji F, Gu X, Microchem J., 64, 93 (2000)

[10] Zaijun L, Jiaomai P, Jan T, Anal. Chim. Acta, 445, 153 (2001)

[11] McMahon M, Regan F, Hughes H, Food Chem., 97, 411 (2006)

[12] Zaijun L, Jian T, Huizhen L, Xia Z, Rui Y, J. Food Compos. Anal., 20, 1 (2007)

[13] Xia Z, Zaijun L, Rui Y, Huizhen L, Anal. Lett., 39, 863 (2006)

[14] Zaijun L, Xia Z, Huizhen L, Rui Y, Commun. Soil Sci. Plant Anal., 39, 461 (2008)

[15] Sargar BM, Anuse MA, J. Anal. Chem., 60, 404 (2005)

[16] Shida J, Takahashi Y, Ojima K, Matsuo T, Bunseki Kagaku, 33, 143 (1984)

[17] Kan M, Nasu T, Taga M, Anal. Sci., 5, 707 (1989)

[18] Soylak M, Unsal YE, Kızıl N, Aydin A, Food Chem. Toxicol., 48, 517 (2010)

[19] Gu X, Zhou T, Anal. Lett., 29, 463 (1996)

[20] Soylak M, Erdogan ND, Elci L, J. Chin. Chem. Soc., 51, 703 (2004)

[21] Goto K, Taguchi S, Anal. Sci., 9, 1 (1993)

[22] Divrikli U, Soylak M, Dogan M, Chem. Anal., 45, 257 (2000)

[23] Nakano M, Sekiguchi C, Wakabayashi H, Shimada K, Bunseki Kagaku, 33, 188 (1983)

[24] Soylak M, Sahin U, Elci L, Anal. Acta Chim., 322, 111 (1996)

[25] Zhang PF, Gao HW, Shen NK, Asian J. Chem., 10, 767 (1998)

[26] Ueno K, Imamura T, Cheng KL, Handbook of Organic Analytical Reagents, 2nd edition, 1999, pp. 39-357.

[27] Aydin FA, Soylak M, Talanta, 73, 134 (2007)

[28] Soylak M, Unsal YE, Tuzen M, Yilmaz E, Food Chem. Toxicol., 49, 1796 (2011)

[29] Tuzen M, Soylak M, Elci L, Dogan M, Anal. Lett., 37, 1185 (2004)

[30] Mahmudov KT, Aliyeva RA, Hamidov SZ, Chyragov FM, Mardanova SR, Kopylovich MN, Pombeiro AJL, Am. J. Anal. Chem., 3, 790 (2012)

[31] Duran C, Ozdes D, Bulut VN, Tufekci M, Soylak M, J. AOAC Int., 94, 286 (2011)

[32] Soylak M, Divrikli U, Elci L, Dogan M, Kuwait J. Sci. Eng., 25, 389 (1998)

[33] Shanbhag B, Gosalia R, Asian J. Chem., 20, 2633 (2008)

[34] Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, Desalination, 281, 226 (2011)

[35] Karve M, Rajgor RV, Sep. Sci. Technol., 42(10), 2255 (2007)

[36] Soylak M, Unsal YE, Tuzen M, Food Chem. Toxicol., 49, 1183 (2011)

[37] Soylak M, Elci L, Dogan M, Kuwait J. Sci. Eng., 24, 87 (1997)

[38] Zeinali N, Ghaedi M, Shafie G, J. Ind. Eng. Chem., 20(5), 3550 (2014)

[39] Ghaedi M, Parham H, Moghadam M, Mortazavi K, Soylak M, Ann. Chim., 96, 689 (2006)

[40] Samaddar P, Sen K, J. Ind. Eng. Chem., 20(4), 1209 (2014)

[41] Gokturk G, Delzendeh M, Volkan M, Spectroc. Acta, 55B, 1063 (2000)

[42] El-Shahawi MS, Hamza A, Al-Sibaai AA, Bashammakh AS, Al-Saidi HM, J. Ind. Eng. Chem., 19(2), 529 (2013)

[43] Kumbasar RA, J. Ind. Eng. Chem., 18(6), 2076 (2012)

[44] Soylak M, Asian J. Chem., 15, 1780 (2003)

[45] Karadas CD, Kara Instrum. Sci. Technol., 42, 548 (2014)

[46] Ueda J, Kitadani T, Anal. Sci., 5, 181 (1989)