화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.26, 270-276, June, 2015
DOI10.1016/j.jiec.2014.11.039  Export Citation
Anticorrosion potential of diethylenetriaminepentakis (methylphosphonic) acid on carbon steel in hydrochloric acid solution
H. Bouammali1, 2, C. Jama3, K. Bekkouch2, A. Aouniti1, 4, B. Hammouti1, 4, and F. Bentiss3, 5, †
  • 1Laboratoire de Chimie Analytique et Environnement, LCAE-URAC18, Faculte des Sciences, Universite Mohammed, Ier B.P. 4808, M-60000, Oujda, Morocco, Korea
  • 2Laboratoire de Chimie du Solide Minerale (LCSM), Faculte des Sciences, Universite Mohammed Ier B.P. 717, M-60000, Oujda, Morocco
  • 3UMET-PSI, CNRS UMR 8207, ENSCL, Universite Lille I, CS 90108, F-59652, Villeneuve d‘Ascq Cedex, France
  • 4, Korea
  • 5Laboratoire de Catalyse et de Corrosion des Materiaux (LCCM), Faculte des Sciences, Universite Chouaib Doukkali, B.P. 20, M-24000, El Jadida, Morocco
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The inhibition ability of diethylenetriaminepentakis(methylphosphonic) acid (DTMP) against carbon steel corrosion in 1 M HCl at 30 °C was evaluated by weight loss, ac impedance and electron probe microanalyser (EPMA) methods. The experimental results showed that DTMP was a good inhibitor for the steel corrosion in 1 M HCl medium and its inhibition efficiency increased with the inhibitor concentration. Data, obtained from ac impedance measurements, were analysed to model the corrosion inhibition process through appropriate equivalent circuit models. Adsorption of DTMP on the carbon steel surface followed the Langmuir adsorption isotherm. Surface analysis supported the formation of a protective inhibitor film on the carbon steel surface.
Keywords:Organic phosphonic acid;Carbon steel;Hydrochloric acid;Corrosion inhibition;Adsorption
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