화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.26, 364-369, June, 2015
DOI10.1016/j.jiec.2014.12.010  Export Citation
Sorptive removal of heavy metals with nano-sized carbon immobilized alginate beads
Woosik Jung, Byong-Hun Jeon, Dong-Wan Cho1, Hyun-Seog Roh1, Yunchul Cho2, Sun-Joon Kim, and Dae Sung Lee3, †
  • Department of Natural Resources and Environmental Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 133-791, South Korea
  • 1Department of Environmental Engineering, Yonsei University, 1 Yonseidae-gil, Wonju 220-710, South Korea
  • 2Department of Environmental Engineering, Daejeon University, 62 Daehak-ro, Dong-gu, Daejeon 300-716 South Korea
  • 3Department of Energy and Mineral Resources Engineering, Dong-A University, 37 Nakdong-Daero, Busan 604-714, South Korea
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A composite adsorbent prepared by immobilizing graphite nano-sized carbon in alginate beads (NCB) was used for the removal of Co(II) and Ni(II) from aqueous solution. Kinetic studies showed that adsorption process reached equilibrium within 8 h at an initial concentration of 10 mg/L and sorption process was well explained by pseudo second order kinetic model. The Freundlich isotherm model correlated well with the adsorption isotherms of Co(II) and Ni(II) onto NCBs. The experimental results showed that the removal of Co(II) and Ni(II) ions from the solution was likely due to ion exchange with calcium(II) ions present in the alginate beads.
Keywords:Cobalt;Nickel;Graphite nano-sized carbon;Alginate;Ion exchange
  1. Papageorgiou SK, Katsaros FK, Kouvelos EP, Nolan JW, Le Deit H, Kanellopoulos NK, J. Hazard. Mater., 137(3), 1765 (2006)
  2. Ge Y, Li Z, Kong Y, Song Q, Wang K, J. Ind. Eng. Chem., 20(6), 4429 (2014)
  3. Jin L, Bai RB, Langmuir, 18(25), 9765 (2002)
  4. Moore JW (Ed.), Inorganic Contaminants of Surface Water Residuals and Monitoring Priorities, Springer-Verlag, New York, NY, 1994.
  5. Bhattacharyya KG, Sen Gupta S, Sep. Sci. Technol., 42(15), 3391 (2007)
  6. Javadian H, J. Ind. Eng. Chem., 20(6), 4233 (2014)
  7. Akhtar N, Iqbal J, Iqbal M, J. Hazard. Mater., 108(1-2), 85 (2004)
  8. WHO, in: WHO (Ed.), Guidelines for Drinking Water Quality, Incorporating First Aaddendum, WHO, Geneva, 2006.
  9. Forstner U, Wittman GTW, Metal Pollution in the Aquatic Environment, Springer-Verlag, New York, NY, 1981.
  10. Schiewer S, Volesky B, Biosorption Processes for Heavy Metal Removal, ASM Press, Washington D.C., 2000.
  11. Volesky B, Sorption and Biosorption, BV, Sorbex, Inc., Quebec, 2003.
  12. Franklin MJ, Douthit SA, McClure MA, J. Bacteriol., 186, 4759 (2004)
  13. Haug A, Smidsrod O, Acta Chem. Scand., 24, 843 (1970)
  14. Papageorgiou SK, Kouvelos EP, Favvas EP, Sapalidis AA, Romanos GE, Katsaros FK, Carb. Res., 345, 469 (2010)
  15. Papageorgiou SK, Kouvelos EP, Katsaros FK, Desalination, 224(1-3), 293 (2008)
  16. Papageorgiou SK, Katsaros FK, Kouvelos EP, Kanellopoulos NK, J. Hazard. Mater., 162(2-3), 1347 (2009)
  17. Athanasekou CP, Papageorgiou SK, Kaselouri V, Katsaros FK, Kakizis NK, Sapalidis AA, Kanellopoulos NK, Microporous Mesoporous Mater., 120(1-2), 154 (2009)
  18. Papageorgiou SK, Katsaros FK, Favvas EP, Romanos GE, Athanasekou CP, Beltsios KG, Tzialla P, Falaras, Water Res., 46(6), 1858 (2012)
  19. Khan MA, Jung W, Kwon OH, Jung YM, Paeng KJ, Cho SY, Jeon BH, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.01.043., 2 (2014)
  20. Kim SH, Lee KH, Kim DH, Park JP, Kim JH, Cho SY, Indoor Built Environ., 21, 837 (2012)
  21. Gupta VK, Rastogi A, Nayak A, J. Colloid Interface Sci., 342, 533 (2010)
  22. Bayramoglu G, Arica MY, Bioresour. Technol., 100(1), 186 (2009)
  23. Googerdchian F, Moheb A, Emadi R, Chem. Eng. J., 200-202, 471 (2012)
  24. Khan MA, Gee E, Choi J, Kumar M, Jung W, Timmes TC, Kim HC, Jeon BH, Chem. Eng. Commun., 201(3), 403 (2014)
  25. Lagergren S, Handlingar Band, 24, 1 (1898)
  26. Ho YS, Ofomaja AE, J. Hazard. Mater., 129(1-3), 137 (2006)
  27. Bayramoglu G, Arica MY, Bioresour. Technol., 100(1), 186 (2009)
  28. Goswami R, Deb P, Thakur R, Sarma KP, Basumallick A, Sep. Sci. Technol., 46(6), 1017 (2011)
  29. Kim KH, Keller AA, Yang JK, Colloids Surf. A: Physicochem. Eng. Asp., 425, 6 (2013)
  30. Sureshkumar MK, Das D, Mallia MB, Gupta PC, J. Hazard. Mater., 184(1-3), 65 (2010)
  31. McKay G, Otterburn MS, Sweeney AG, Water Res., 14, 21 (1980)
  32. Lazaridis NK, Charalambous C, Water Res., 39, 4385 (2005)
  33. Bhatnagar A, Vilar VJP, Santos JC, Botelho CMS, Boaventura RAR, Chem. Eng. J., 200-202, 365 (2012)
  34. Crist RH, Martin JR, Carr D, Watson JR, Clarke HJ, Environ. Sci. Technol., 28, 1859 (1994)
  35. Schiewer S, Volesky B, Environ. Sci. Technol., 29, 3049 (1995)
  36. Rao GP, Lu C, Su F, Sep. Purif. Technol., 58(1), 224 (2007)
  37. Mubarak NM, Sahu JN, Abdullah EC, Jayakumar NS, Sep. Purif. Technol., 43, 311 (2014)