On-line flame AAS determination of traces Cd(II) and Pb(II) in water samples using thiol-functionalized SBA-15 as solid phase extractant

S.L. Zhao; F.S. Chen; J. Zhang; S.B. Ren; H.D. Liang; S.S. Li

Journal of Industrial and Engineering Chemistry, Vol.27, 362-367, July, 2015

DOI10.1016/j.jiec.2015.01.015 Export Citation

On-line flame AAS determination of traces Cd(II) and Pb(II) in water samples using thiol-functionalized SBA-15 as solid phase extractant

S.L. Zhao^†, F.S. Chen¹, J. Zhang, S.B. Ren, H.D. Liang^†, and S.S. Li

School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000, Zhejiang, PR China
¹School of Chemical and Environmental Engineering, Jiujiang University, Jiujiang 332005, Jiangxi, PR China

E-mail:,

Mesoporous thiol-functionalized SBA-15 was investigated as a microcolumn packed material for the on-line preconcentration of trace amounts of Pb(II) and Cd(II) in water samples before their flame AAS determination. The results indicated that the proposed method was tolerant to the coexistence ions, offered good linearity and the achievable enhancement factors were 34 for Pb(II) and 41 for Cd(II), and the detection limits (3σ) of 0.22 μg L-1 and 0.11 μg L-1 and the precision (RSD) for 11 replicate determination of 30 μg L?1 Pb(II) and 20 μg L-1Cd(II) were 0.4% and 0.3%, respectively.

Keywords:Lead;Cadmium;Determination;Thiol-functionalized SBA-15;Flame AAS

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Valfredo AL, Emanuel V, Water, 40, 268 (2012)
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Tavallali H, Yazdandoust S, Yazdandoust M, Water, 38, 242 (2010)
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Fang GZ, Tan J, Yan XP, Anal. Chem., 77, 1734 (2005)
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Xie FZ, Lin XC, Wu XP, Xie ZH, Talanta, 74, 836 (2008)
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de Pena YP, Lopeza W, Burgueıa M, Burgueıa JL, Anal. Chim. Acta, 438, 259 (2001)
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Zhao SL, Liang HD, Yan H, Yan ZZ, Chen SQ, Chen MX, Water, 38, 146 (2010)
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Liang HD, Han DM, Anal. Lett., 39, 2285 (2006)
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Soylak M, Soylak Z, J. Ind. Eng. Chem., 20(2), 581 (2014)
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[Referenced By]

[1] Fang Z, Flow Injection Separation and Preconcentration, Wiley, New York, 1993.

[2] Ojeda CB, Rojas FS, Microchim. Acta, 177, 1 (2012)

[3] Valfredo AL, Emanuel V, Water, 40, 268 (2012)

[4] Wasey A, Bansal RK, Puri BK, Kano G, Microchim. Acta, 84, 417 (1984)

[5] Tavallali H, Yazdandoust S, Yazdandoust M, Water, 38, 242 (2010)

[6] Roman ES, Talanta, 32, 1083 (1985)

[7] Fang GZ, Tan J, Yan XP, Anal. Chem., 77, 1734 (2005)

[8] Zhao SL, Yan H, Liang HD, Yan ZZ, Lin YQ, Spectrosc. Lett., 43, 122 (2010)

[9] Xie FZ, Lin XC, Wu XP, Xie ZH, Talanta, 74, 836 (2008)

[10] Ali A, Yin X, Shen H, Ye Y, Gu X, Anal. Chim. Acta, 392, 283 (1999)

[11] de Pena YP, Lopeza W, Burgueıa M, Burgueıa JL, Anal. Chim. Acta, 438, 259 (2001)

[12] Shokrollahi A, Zahedi M, Niknam K, Soylak M, Water, 38, 1047 (2010)

[13] Lemos VA, Novaes CG, Lima AD, Vieira DR, J. Hazard. Mater., 155(1-2), 128 (2008)

[14] Kumar DH, Ramana DKV, Harinath Y, Seshaiah K, Wang MC, J. Agric. Food Chem., 59, 11352 (2011)

[15] Duran C, Gundogdu A, Bulut VN, Soylak M, Elci L, Senturk HB, Tufekci M, J. Hazard. Mater., 146(1-2), 347 (2007)

[16] de Pena YP, Gallego M, Valcarcel M, J. Anal. At. Spectrom., 12, 453 (1997)

[17] Ghaedi M, Montazerozohori M, Rahimi N, Biysreh MN, J. Environ. Anal. Chem., 93, 1525 (2013)

[18] Pereira MDG, Arruda MAZ, Microchim. Acta, 146, 215 (2004)

[19] Ensafi AA, Ghaderi AR, J. Hazard. Mater., 148(1-2), 319 (2007)

[20] Ensafi AA, Khayamlan T, Karbasi MH, Anal. Sci., 19, 953 (2003)

[21] Zhao SL, Liang HD, Yan H, Yan ZZ, Chen SQ, Chen MX, Water, 38, 146 (2010)

[22] Zhu XD, Liang HD, Zhao SL, Yan H, Han DM, Int. J. Environ. Anal. Chem, 88, 689 (2008)

[23] Liang HD, Han DM, Anal. Lett., 39, 2285 (2006)

[24] Barbosa AF, Segatelli MG, Pereira AC, de A, Santos S, Kubota LT, Luccas PO, Tarley CRT, Talanta, 71, 1512 (2007)

[25] Soylak M, Soylak Z, J. Ind. Eng. Chem., 20(2), 581 (2014)

[26] Latorre CH, Mendez JA, Garcia JB, Martin SG, Crecente RMP, Anal. Chim. Acta, 749, 16 (2012)

[27] Walcarius A, Mercier L, J. Mater. Chem., 20, 4478 (2010)

[28] Bae JA, Hwang SH, Song KC, Jeon JK, Ko YS, Yim JH, J. Nanosci. Nanotechnol., 10, 290 (2010)

[29] Mureseanu M, Reiss A, Stefanescu I, David E, Parvulescu V, Renard G, Hulea V, Chemosphere, 73, 1499 (2008)

[30] Aguado J, Arsuaga JM, Arencibia A, Microporous Mesoporous Mater., 109, 513 (2008)

[31] Sierra I, Quintanilla DP, Chem. Soc. Rev., 42, 3792 (2013)

[32] Chen D, Hu B, Huang C, Talanta, 78, 491 (2009)

[33] Huang CZ, Hu B, Jiang ZC, Spectroc. Acta Pt. B-Atom. Spectr., 62, 454 (2007)

[34] Wiberg VE, Wiberg N, Holleman AF, Inorganic Chemistry, Academic Press, New York, 2001.

[35] Misra AK, Agnihotri G, Synth. Commun., 34, 1079 (2004)

[36] Fardmousavi O, Faghihian H, C. R. Chimie, 17, 1203 (2014)

[37] Siaka M, Owens CM, Birch GF, Anal. Lett., 31, 703 (1998)

[38] Sham KW, Mustafa T, Tasneem GK, Mustafa S, Baki H, Food Chem., 152, 75 (2014)