Silver loading on poly(ethylene terephthalate) fabrics using silver carbamate via thermal reduction

Wan-Gyu Kwak; Man Hwan Oh; Seung-Yeol Son; Myoung-Seon Gong

Macromolecular Research, Vol.23, No.6, 509-517, June, 2015

DOI10.1007/s13233-015-3069-2 Export Citation

Silver loading on poly(ethylene terephthalate) fabrics using silver carbamate via thermal reduction

Wan-Gyu Kwak, Man Hwan Oh, Seung-Yeol Son¹, and Myoung-Seon Gong^†

Department of Nanobiomedical Science and BK21 PLUS NBM Global Research Center for Regenerative Medicine, Dankook University, Chungnam, 330-714, Korea
¹Department of Microbiology, Dankook University, Chungnam, 330-714, Korea

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Silver-coated poly(ethylene terephthalate) (PET) fabrics were prepared through the deposition of silver nanoparticles (AgNPs) generated from thermal reduction of silver 2-ethylhexylcarbamate. The PET fabrics modified with 3-mercaptopropyltriethoxysilane, which acts as an anchor for the AgNPs, were padded with a solution of silver 2-ethylhexylcarbamate in methanol, and were then reduced for in situ generation of Ag-NPs only by heating at 130 °C. The PET/Ag fabrics were characterized by using scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), and water contact angle analysis, and by measuring the electrical conductivity and antibacterial activity. A continuous layer of AgNPs with a size from 30 to 100 nm was assembled on the PET fabrics. The PET/Ag imparts high conductivity to the textiles with an electric resistance as low as 3.44±0.12 Ω, and the antibacterial effects of the treated PET fabric against Escherichia coli O157:H7 (ATCC 43889) and Staphylococcus aureus (ATCC 25923) were examined and were found to be excellent.

Keywords:silver carbamate;thermal reduction;pet fabric;composites;silver nanoparticles

[References]

Shimoyama S, Taguchi S, Ota T, JP Patent 212845-A (2001).
Fujimoto K, Kato J, EP Patent 1033422-A (1999).
Brooks DW, Giles GA, PET Packaging Technology, Sheffield Academic, Sheffield, 2002.
Scheirs J, Long TE, in Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters, John Wiley & Sons, Ltd., New York, 2003, Chap. 1, p 3
Jiang SX, Qi WF, Guo HH, Zhang L, Surf. Coat. Technol., 204, 3662 (2010)
Sureshkumar M, Siswanto DY, Lee CK, J. Mater. Chem., 20, 6948 (2010)
Moon JH, Kim KH, Choi HW, Lee SW, Park SJ, Ultramicroscopy, 108, 1307 (2008)
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Joon J, Seung KR, J. Mater. Process. Technol., 180, 66 (2006)
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Bambauer R, Mestres P, Schiel R, Klinkmann J, Sioshansi P, Artif. Organs, 21, 1039 (1997)
Chen YH, Hsu CC, He JL, Surf. Coat. Technol., 232, 868 (2013)
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Shin US, Hong HK, Kim HW, Gong MS, Bull. Korean Chem. Soc., 32, 1583 (2011)
Park HS, Park HS, Gong MS, Bull. Korean Chem. Soc., 31, 2575 (2010)
Alessio R, Dell’Amico DB, Calderazzo F, Englert U, Guarini A, Labella L, Strasser P, Helv. Chim. Acta, 88, 219 (1998)
Allahyarzadeh V, Montazer M, Nejad NH, Samadi N, J. Appl. Polym. Sci., 129(2), 892 (2013)
Kwak WG, Oh MH, Gong MS, Carbohydr. Polym., 115, 317 (2015)
Liao YA, Wang YQ, Feng XX, Wang WC, Xu FJ, Zhang LQ, Mater. Chem. Phys., 121(3), 534 (2010)
Lu Y, Jiang S, Huang Y, Synth. Met., 160, 419 (2010)
Lu Y, Jiang S, Huang Y, Surf. Coat. Technol., 204, 2829 (2010)
Virendra K, Claude J, Jerome P, Reza J, Farzaneh AK, J. Biomed. Mater. Res., 101, 1121 (2013)
Karthik R, Swaminatha KI, Mark KK, George C, Phillip BJ, Igor L, J. Eng. Fibers Fabrics, 3, 1 (2008)
Line L, Gong WH, Wang X, Li X, Wang S, Mater. Lett., 65, 1375 (2011)
Xue CH, Chen J, Yin W, Jia ST, Ma JZ, Appl. Surf. Sci., 258(7), 2468 (2012)

[Referenced By]

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[1] Shimoyama S, Taguchi S, Ota T, JP Patent 212845-A (2001).

[2] Fujimoto K, Kato J, EP Patent 1033422-A (1999).

[3] Brooks DW, Giles GA, PET Packaging Technology, Sheffield Academic, Sheffield, 2002.

[4] Scheirs J, Long TE, in Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters, John Wiley & Sons, Ltd., New York, 2003, Chap. 1, p 3

[5] Jiang SX, Qi WF, Guo HH, Zhang L, Surf. Coat. Technol., 204, 3662 (2010)

[6] Sureshkumar M, Siswanto DY, Lee CK, J. Mater. Chem., 20, 6948 (2010)

[7] Moon JH, Kim KH, Choi HW, Lee SW, Park SJ, Ultramicroscopy, 108, 1307 (2008)

[8] Morones JR, Elechiguerra JL, Cammacho A, Holt K, Kouri JB, Ramirez JT, Yacaman NJ, Nanotechnology, 16, 2346 (2005)

[9] Hong YK, Lee CY, Jeong CK, Curr. Appl. Phys., 1, 439 (2001)

[10] Joon J, Seung KR, J. Mater. Process. Technol., 180, 66 (2006)

[11] El-Rafie MH, Mohamed AA, Shaheen TI, Hebeish A, Carbohydr. Polym., 80, 779 (2010)

[12] Perelshtein I, Applerot G, Perkas N, Guibert G, Mikhailov S, Nanotechnology, 19, 245705 (2008)

[13] Wang RX, Tao XM, Wang Y, Wang GF, Shang SM, Surf. Coat. Technol., 204, 1206 (2010)

[14] Sioshansi P, Artif. Organs, 18, 266 (1994)

[15] Bambauer R, Mestres P, Schiel R, Klinkmann J, Sioshansi P, Artif. Organs, 21, 1039 (1997)

[16] Chen YH, Hsu CC, He JL, Surf. Coat. Technol., 232, 868 (2013)

[17] Serghini-Monim S, Norton PR, Puddephatt RJ, Pollard KD, Rasmussen JR, J. Phys. Chem. B, 102(8), 1450 (1998)

[18] Gerenser LJ, J. Vac. Sci. Technol. A, 8, 3682 (1990)

[19] Gerenser LJ, J. Vac. Sci. Technol. A, 6, 2897 (1988)

[20] Jiang XX, Shen WJ, in The Fundamental and Practice of Electroless Plating, 1st ed., Defense and Industry Publishing House, Beijing, 2000, p 361.

[21] Kim KA, Cha JR, Gong MS, Bull. Korean Chem. Soc., 34, 505 (2013)

[22] Kim KA, Gong MS, Park CK, Bull. Korean Chem. Soc., 33, 3987 (2012)

[23] Shin US, Hong HK, Kim HW, Gong MS, Bull. Korean Chem. Soc., 32, 1583 (2011)

[24] Park HS, Park HS, Gong MS, Bull. Korean Chem. Soc., 31, 2575 (2010)

[25] Alessio R, Dell’Amico DB, Calderazzo F, Englert U, Guarini A, Labella L, Strasser P, Helv. Chim. Acta, 88, 219 (1998)

[26] Allahyarzadeh V, Montazer M, Nejad NH, Samadi N, J. Appl. Polym. Sci., 129(2), 892 (2013)

[27] Kwak WG, Oh MH, Gong MS, Carbohydr. Polym., 115, 317 (2015)

[28] Liao YA, Wang YQ, Feng XX, Wang WC, Xu FJ, Zhang LQ, Mater. Chem. Phys., 121(3), 534 (2010)

[29] Lu Y, Jiang S, Huang Y, Synth. Met., 160, 419 (2010)

[30] Lu Y, Jiang S, Huang Y, Surf. Coat. Technol., 204, 2829 (2010)

[31] Virendra K, Claude J, Jerome P, Reza J, Farzaneh AK, J. Biomed. Mater. Res., 101, 1121 (2013)

[32] Karthik R, Swaminatha KI, Mark KK, George C, Phillip BJ, Igor L, J. Eng. Fibers Fabrics, 3, 1 (2008)

[33] Line L, Gong WH, Wang X, Li X, Wang S, Mater. Lett., 65, 1375 (2011)

[34] Xue CH, Chen J, Yin W, Jia ST, Ma JZ, Appl. Surf. Sci., 258(7), 2468 (2012)