천연가스의 탄화수소 이슬점 측정방법 비교 연구

이강진; 하영철; 허재영; 우진춘; 김용두; 배현길; Kang-Jin Lee; Young-Cheol Ha; Jae-Young Her; Jin-Chun Woo; Yong-Doo Kim; Hyun-Kil Bae

Korean Chemical Engineering Research, Vol.53, No.4, 496-502, August, 2015

DOI10.9713/kcer.2015.53.4.496 Export Citation

천연가스의 탄화수소 이슬점 측정방법 비교 연구

A Study on the Comparison of Methods for the Measurement of Hydrocarbon Dew Point of Natural Gas

이강진^†, 하영철, 허재영, 우진춘¹, 김용두¹, 배현길¹

한국가스공사 연구개발원 설비기술연구센터, 426-790 경기 안산시 상록구 수인로 1248
¹한국표준과학연구원 삶의질측정표준본부 대기환경표준센터

Kang-Jin Lee^†, Young-Cheol Ha, Jae-Young Her, Jin-Chun Woo¹, Yong-Doo Kim¹, and Hyun-Kil Bae¹

Gas Facility Technology Center, R & D Division, Korea Gas Corporation, 1248 Suin-ro, Sangnok-gu, Ansan, Gyunggi 426-790, Korea
¹Gas Analysis, Division of Metrology for Quality of Life, Korea Research Institute of Standards and Science, 267 Gajeong-ro, Yuseong-gu, Daejeon 305-340, Korea

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초록

탄화수소 이슬점은 천연가스 응축형태를 특성화하는 가장 일반적이고 자주 이용되는 물성으로 가스 품질 사양의 중요한 항목이다. 탄화수소 이슬점은 미량의 고탄화수소 성분에도 매우 민감한 것으로 알려져 있어, 특히 천연가스를 공급하는 가스 회사 입장에서는 기존 합의된 가스 사양을 만족하는 것 뿐만 아니라, 발생된 탄화수소 응축물에 의해 운영설비 및 안전에 심각한 문제를 일으킬 수 있으므로 탄화수소 이슬점을 정확하게 구하는 절차를 확립하는 것이 중요하다. 본 연구에서는 실제 현장조건 하에서 탄화수소 이슬점을 측정하기 위해 냉각 거울 방식의 이슬점 측정기를 설치, 운영하였으며, 측정된 이슬점 온도는 가스분석기에 의해 분석된 조성 및 천연가스 산업계에서 인정된 상태방정식을 이용하여 계산된 이슬점 온도와 비교하였다. 시험 결과 탄화수소 이슬점 측정기는 매우 안정되게 이슬점을 측정하였으며, 이슬점 측정기를 검증하기 위한 시험 가스로는 순수 프로판 가스가 적정하였다. 제조 표준가스 및 실제가스의 측정결과를 가스분석기에 의한 간접 측정 결과와 비교시에도 적정한 범위 내에서 일치하는 것을 확인하였다.

Hydrocarbon dew point(HCDP), a property which is the most generally used for describing natural gas condensation, is a very important parameter of natural gas quality specifications. HCDP is strongly influenced by the concentration of the heavier hydrocarbon components, especially C6+, so, along with compliance with gas quality specifications, build up of procedures for obtaining accurate HCDP is essential for gas transmission company, because hydrocarbon condensation present may cause serious operational and safety problems. This study has been carried out in an attempt to measure HCDP accurately by the automatic hydrocarbon dew point meter under the actual field conditions. Measured HCDP also has been compared with calculated HCDP using the composition determined by gas chromatograph and industry accepted equation of state at multiple pressures, along with the cricondentherm. The test results are 1) the automatic hydrocarbon dew point meter was able to measure stable HCDP continuously 2) the automatic hydrocarbon dew point meter has been performed reference measurement by pure propane with a known dew point from literature, and 3) A meaningful differences was observed when comparing the automatic hydrocarbon dew point meter and gas chromatograph results for synthetic standard gas mixtures and real gas mixtures.

Keywords:Natural Gas Quality;Hydrocarbon Dew Point(HCDP);Cricondentherm;Gas Chromatograph

[References]

Cirka GE, Soderberg HC, Dew Point Testing of Natural Gas, NOVA Corporation of Alberta, Ametek Technical Paper (1990).
Ha Y, Lee S, Korean Chem. Eng. Res., 49(1), 35 (2011)
NGC, White Paper on Liquid Hydrocarbon Dropout in Natural Gas Infrastructure, NGC+ Gas Quality White Paper PL 04-3-000 (2004).
Bryant N, Arizmendi J, Kane A, Laughton A, Williams A, Gas Quality Specification of PNG and Facility Adjustment, Advantica Report 7202(2008).
ISO 14532, Natural Gas-Vocabulary, International Organization for Standardization(2001).
ISO 13686, Natural Gas-Quality Designation, International Organization for Standardization(1998).
Bloomer OT, Gami DC, Parent JD, Physical-Chemical Properties of Methane-Ethane Mixtures, Institute of Gas Technology (now “Gas Technology Institute”, in Chicago), Research Bulletin No. 17(1953).
Shooshtari SHR, Shahsavand A, Korean J. Chem. Eng., 31(10), 1845 (2014)
Andrew B, Martin M, Gergely V, Richard M, Chris C, Andrew S, Andy B, Mike B, Andy R, Dave L, Andrew L, Comparison of Methods for the Measurement of Hydrocarbon Dew Point of Natural Gas, National Physical Laboratory Report, AS 3(2007).
Nasrifar K, Bolland O, Moshfeghian M, Energy Fuels, 19(2), 561 (2005)
Ametek, Model 241CE ll Hydrocarbon Dewpoint Analyzer, Ametek User Manual(2009).
ISO 6141, Gas Analysis-Requirements for Certificates for Calibration Gases and Gas Mixtures, International Organization for Standardization(2000).
ISO 6143, Gas Analysis-Comparisons Methods for Determining and Checking the Composition of Calibration Gas Mixtures, International Organization for Standardization(2001).
Ha Y, Lee S, Her J, Lee K, Lee S, Korean Chem. Eng. Res., 47(5), 565 (2009)
ISO 10715, Natural Gas-Sampling Guidelines, International Organization for Standardization(2000).
ISO 6974-5, Natural gas-Determination of Composition with Defined Uncertainty by Gas Chromatography-Part 5 : Determination of Nitrogen, Carbon dioxide and C1 to C5 and C6+ Hydrocarbons for a Laboratory and On-line Process Application using Three Columns, International Organization for Standardization(2000).
ISO 23874, Natural Gas-Gas Chromatographic Requirement for Hydrocarbon Dewpoint Calculation, International Organization for Standardization(2006).
GERG Project 1.52, Comparing and Defining a Relation between Experimental and Calculating Techniques for Hydrocarbon Dew-Point, European Gas Research Group(2009).
Lee KJ, Her JY, Lee SM, Lee SJ, Ha YC, Ryu GC, Lee CY, Kim GH, Yun EG, Establishment of Measurement Standards for the Quality Assurance of PNG/SNG and Study on the Improvement Plan of Field Measurement Facilities, Korea Gas Corporation Report(2013).

[1] Cirka GE, Soderberg HC, Dew Point Testing of Natural Gas, NOVA Corporation of Alberta, Ametek Technical Paper (1990).

[2] Ha Y, Lee S, Korean Chem. Eng. Res., 49(1), 35 (2011)

[3] NGC, White Paper on Liquid Hydrocarbon Dropout in Natural Gas Infrastructure, NGC+ Gas Quality White Paper PL 04-3-000 (2004).

[4] Bryant N, Arizmendi J, Kane A, Laughton A, Williams A, Gas Quality Specification of PNG and Facility Adjustment, Advantica Report 7202(2008).

[5] ISO 14532, Natural Gas-Vocabulary, International Organization for Standardization(2001).

[6] ISO 13686, Natural Gas-Quality Designation, International Organization for Standardization(1998).

[7] Bloomer OT, Gami DC, Parent JD, Physical-Chemical Properties of Methane-Ethane Mixtures, Institute of Gas Technology (now “Gas Technology Institute”, in Chicago), Research Bulletin No. 17(1953).

[8] Shooshtari SHR, Shahsavand A, Korean J. Chem. Eng., 31(10), 1845 (2014)

[9] Andrew B, Martin M, Gergely V, Richard M, Chris C, Andrew S, Andy B, Mike B, Andy R, Dave L, Andrew L, Comparison of Methods for the Measurement of Hydrocarbon Dew Point of Natural Gas, National Physical Laboratory Report, AS 3(2007).

[10] Nasrifar K, Bolland O, Moshfeghian M, Energy Fuels, 19(2), 561 (2005)

[11] Ametek, Model 241CE ll Hydrocarbon Dewpoint Analyzer, Ametek User Manual(2009).

[12] ISO 6141, Gas Analysis-Requirements for Certificates for Calibration Gases and Gas Mixtures, International Organization for Standardization(2000).

[13] ISO 6143, Gas Analysis-Comparisons Methods for Determining and Checking the Composition of Calibration Gas Mixtures, International Organization for Standardization(2001).

[14] Ha Y, Lee S, Her J, Lee K, Lee S, Korean Chem. Eng. Res., 47(5), 565 (2009)

[15] ISO 10715, Natural Gas-Sampling Guidelines, International Organization for Standardization(2000).

[16] ISO 6974-5, Natural gas-Determination of Composition with Defined Uncertainty by Gas Chromatography-Part 5 : Determination of Nitrogen, Carbon dioxide and C1 to C5 and C6+ Hydrocarbons for a Laboratory and On-line Process Application using Three Columns, International Organization for Standardization(2000).

[17] ISO 23874, Natural Gas-Gas Chromatographic Requirement for Hydrocarbon Dewpoint Calculation, International Organization for Standardization(2006).

[18] GERG Project 1.52, Comparing and Defining a Relation between Experimental and Calculating Techniques for Hydrocarbon Dew-Point, European Gas Research Group(2009).

[19] Lee KJ, Her JY, Lee SM, Lee SJ, Ha YC, Ryu GC, Lee CY, Kim GH, Yun EG, Establishment of Measurement Standards for the Quality Assurance of PNG/SNG and Study on the Improvement Plan of Field Measurement Facilities, Korea Gas Corporation Report(2013).