Korean Journal of Materials Research, Vol.25, No.6, 293-299, June, 2015
질소 이온이 주입된 STS 316L 스테인리스 강에서의 상변화와 집합조직이 내식성에 미치는 영향
Influence of Phase Evolution and Texture on the Corrosion Resistance of Nitrogen Ion Implanted STS 316L Stainless Steel
E-mail:
In this study, nitrogen ions were implanted into STS 316L austenitic stainless steel by plasma immersion ion implantation (PIII) to improve the corrosion resistance. The implantation of nitrogen ions was performed with bias voltages of .5, .10, .15, and .20 kV. The implantation time was 240 min and the implantation temperature was kept at room temperature. With nitrogen implantation, the corrosion resistance of 316 L improved in comparison with that of the bare steel. The effects of nitrogen ion implantation on the electrochemical corrosion behavior of the specimen were investigated by the potentiodynamic polarization test, which was conducted in a 0.5 M H2SO4 solution at 70 oC. The phase evolution and texture caused by the nitrogen ion implantation were analyzed by an X-ray diffractometer. It was demonstrated that the samples implanted at lower bias voltages, i.e., 5 kV and 10 kV, showed an expanded austenite phase, γN, and strong (111) texture morphology. Those samples exhibited a better corrosion resistance.
Keywords:plasma immersion ion implantation(PIII);STS 316L stainless steel;corrosion;residual stress;texture
- Li Y, Wang L, Xu J, Zhang D, Surf. Coat. Technol., 206(8), 2430 (2012)
- Santos JF, Garzon CM, Tschiptschin AP, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 382(2), 378 (2004)
- Yang LJ, Yu HJ, Jiang LJ, Zhu L, Jian XY, Wang Z, J. Power Sources, 195(9), 2810 (2010)
- Dodd CG, Meeker GP, Baumann SM, Norberg JC, Legg KO, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 7-8, 219 (1985)
- Yu LD, Vilaithong T, Suwannakachorn D, Intarasiri S, Thongtem S, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 127-128, 954 (1997)
- Luo Y, Ge S, Tribol. Int., 42(9), 1373 (2009)
- Chen J, Conrad JR, Dodd RA, J. Mater. Process. Technol., 49(1-2), 115 (1995)
- Ibrahim MAM, Korablov SF, Yoshimura M, Corrosion Sci., 44(4), 815 (2002)
- Jones DA, Principles and prevention of corrosion, 2nd ed., Prentice Hall, Upper Saddle River, NJ (2011).
- Kelly RG, Scully JR, Shoesmith DW, Buchheit RG, Electrochemical techniques in corrosion science and engineering, Marcel Dekker, Inc., New York (2003).
- Christiansen T, Somers MAJ, Scr. Mater., 50(1), 35 (2004)
- Li X, Samandi M, Dunne D, Hutchings R, Surf. Coat. Technol., 71(2), 175 (1995)
- Picard S, Memet JB, Sabot R, Grosseau-Poussard JL, Riviere JP, Meilland R, Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., 303(1-2), 163 (2001)
- Blawert C, Weisheit A, Mordike BL, Knoop RM, Surf. Coat. Technol., 85(1-2), 15 (1996)
- Blawert C, Mordike BL, Jiraskova Y, Schneeweiss O, Surf. Coat. Technol., 116-119, 189 (1999)
- Robin A, Martinez GAS, Suzuki PA, Mater. Des., 34, 319 (2012)
- Mandl S, Gunzel R, Richter E, Moller W, Surf. Coat. Technol., 100-101, 372 (1998)
- Tian XB, Zeng ZM, Zhang T, Tang BY, Chu PK, Thin Solid Films, 366(1-2), 150 (2000)
- Templier C, Stinville JC, Villechaise P, Renault PO, Abrasonis G, Riviere JP, Martinavicius A, Drouet M, Surf. Coat. Technol., 204(16-17), 2551 (2010)
- Manova D, Hoche T, Mandl S, Neumann H, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 267(8-9), 1536 (2009)
- Mukherjee S, Chakraborty J, Gupta S, Raole PM, John PI, Rao KRM, Manna I, Surf. Coat. Technol., 156(1), 103 (2002)
- Blawert C, Kalvelage H, Mordike BL, Collins GA, Short KT, Jiraskova Y, Schneeweiss O, Surf. Coat. Technol., 136(1-3), 181 (2001)
- Menthe E, Rie KT, Schultze JW, Simson S, Surf. Coat. Technol., 74(1), 412 (1995)
- Mukherjee S, Raole PM, John PI, Surf. Coat. Technol., 157(2-3), 111 (2002)
- Ma X, Jiang S, Sun Y, Tang G, Sun M, Surf. Coat. Technol., 201(15), 6695 (2007)
- Mukherjee S, Raole PM, Kumar A, Chattoraj I, Rao KRM, Manna I, Surf. Coat. Technol., 186(1-2), 282 (2004)
- Rickerby DS, Jones AM, Bellamy BA, Surf. Coat. Technol., 37(1), 111 (1989)
- Gangopadhyay S, Acharya R, Chattopadhyay AK, Paul S, Vacuum, 84(6), 843 (2010)
- Herranen M, Bauer AD, Carlsson JO, Bunshah RF, Surf. Coat. Technol., 96(2-3), 245 (1997)
- Kuo CT, Lin CR, Lien HM, Thin Solid Films, 290-291, 254 (1996)
- Khorsand S, Raeissi K, Golozar MA, Corrosion Sci., 53(8), 2676 (2011)
- Park H, Szpunar JA, Corrosion Sci., 40(4-5), 525 (1998)
- Kumar BR, Singh R, Mahato B, De PK, Bandyopadhyay NR, Bhattacharya DK, Mater. Charact., 54(2), 141 (2005)
- Song GL, Xu Z, Corrosion Sci., 63, 100 (2012)