화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.32, No.11, 2311-2318, November, 2015
DOI10.1007/s11814-015-0064-4  Export Citation
Mass transfer intensification of nanofluid single drops with effect of temperature
Javad Saien†, and Mahdi Zardoshti
  • Bu-Ali Sina University, 65174, Hamedan, Iran
E-mail:
The hydrodynamics and mass transfer of organic nanofluid single drops in liquid-liquid extraction process were investigated within temperature range of 20 to 40 oC. Nanofluid drops of toluene+acetic acid, containing surface modified magnetite nanoparticles (NPs) with concentration within the range of (0.0005-0.005) wt%, were conducted in aqueous continuous phase. The rate of solute mass transfer was generally enhanced with NPs until about 0.002wt%, and small drops benefited more. The enhancement reached 184.1% with 0.002 wt% of NPs at 40 oC; however, adding more NPs led to the mass transfer to either remain constant or face a reduction, depending on the applied temperature. The mass transfer coefficient was nicely reproduced using a developed correlation for enhancement factor of molecular diffusivity as a function of Reynolds and Schmidt numbers.
Keywords:Liquid-liquid Extraction;Nanofluid;Single Drops;Temperature;Mass Transfer Enhancement
  1. Saien J, Daliri S, Ind. Eng. Chem. Res., 47(1), 171 (2008)
  2. Saien J, Daliri S, Korean J. Chem. Eng., 26(4), 963 (2009)
  3. Saien J, Daliri S, Ind. Eng. Chem. Res., 51(21), 7364 (2012)
  4. Saien J, Daliri S, J. Ind. Eng. Chem., 20(1), 238 (2014)
  5. Saien J, Daliri S, J. Taiwan Inst. Chem. Eng., 45, 808 (2014)
  6. Saien J, Ashrafi F, Ind. Eng. Chem. Res., 48(22), 10008 (2009)
  7. Saien J, Asadabadi S, J. Taiwan Inst. Chem. Eng., 41, 295 (2010)
  8. Saien J, Bamdadi H, Ind. Eng. Chem. Res., 51(14), 5157 (2012)
  9. Saien J, Bamdadi H, Daliri S, J. Ind. Eng. Chem., 21, 1152 (2015)
  10. Bahmanyar A, Khoobi N, Mozdianfard MR, Bahmanyar H, Chem. Eng. Process., 50(11-12), 1198 (2011)
  11. Bahmanyar A, Khoobi N, Moharrer MMA, Bahmanyar H, Chem. Eng. Res. Des., 92(11), 2313 (2014)
  12. Raji-Asadabadi M, Abolghasemi H, Maragheh MG, Davoodi-Nasab P, Chem. Eng. Res. Des., 91(9), 1739 (2013)
  13. Ashrafmansouri SS, Esfahany MN, Int. J. Therm. Sci., 82, 84 (2014)
  14. Lee JK, Koo J, Hong H, Kang YT, Int. J. Refrig., 33, 269 (2010)
  15. Olle B, Bucak S, Holmes TC, Bromberg L, Hatton TA, Wang DIC, Ind. Eng. Chem. Res., 45(12), 4355 (2006)
  16. Asadabadi MR, Abolghasemi H, Maragheh MG, Nasab PD, Korean J. Chem. Eng., 30(3), 733 (2013)
  17. Ramirez LP, Landfester K, Macromol. Chem. Phys., 204, 22 (2003)
  18. Jingjing W, Dengxin L, Energy Procedia, 11, 4794 (2011)
  19. Komati S, Suresh AK, Ind. Eng. Chem. Res., 49, 390 (2009)
  20. Yang K, Peng HB, Wen YH, Li N, Appl. Surf. Sci., 256(10), 3093 (2010)
  21. Wang XQ, Mujumdar AS, Int. J. Therm. Sci., 46, 1 (2007)
  22. Bird RB, Stewart WE, Lightfoot EN, Transport Phenomena, 2nd Ed., Wiley, New York (2007).
  23. Saien J, Moghaddamnia F, Mishi M, Korean J. Chem. Eng., 30(5), 1125 (2013)
  24. Saien J, Pour AR, Asadabadi S, J. Chem. Eng. Data, 59(6), 1835 (2014)
  25. Pak BC, Cho YI, Exp. Heat Transf., 11(2), 151 (1998)
  26. Grace J, Wairegi T, Nguyen T, Chem. Eng. Res. Des., 54, 167 (1976)
  27. Hu S, Kinter R, AIChE J., 1, 42 (1955)
  28. Temos J, Pratt HR, Stevens GW, Chem. Eng. Sci., 51(1), 27 (1996)
  29. Skelland AHP, Interphase mass transfer, in: Science and Practice of Liquid-liquid Extraction, Vol. 1, Thornton JD, Ed., Oxford Science Pub., New York (1992).
  30. Klee AJ, Treybal RE, AIChE J., 2, 444 (1956)
  31. Godson L, Raja B, Mohanlal D, Wongwises S, Renew. Sust. Energ. Rev., 14, 629 (2010)
  32. Mohammed H, Al-aswadi A, Shuaib N, Saidur R, Renew. Sust. Energ. Rev., 15, 2921 (2011)
  33. Nagy E, Feczko T, Koroknai B, Chem. Eng. Sci., 62(24), 7391 (2007)
  34. Fang X, Xuan Y, Li Q, Appl. Phys. Lett., 95, 203108 (2009)
  35. Krishnamurthy S, Bhattacharya P, Phelan PE, Prasher RS, Nano Lett., 6, 419 (2006)
  36. Cui W, Shen Z, Yang J, Wu S, Appl. Therm. Eng., 76, 261 (2015)
  37. Cui W, Bai M, Lv J, Zhang L, Li G, Xu M, Exp. Therm. Fluid Sci., 39, 148 (2012)
  38. Veilleux J, Coulombe SA, J. Appl. Phys., 108, 104316 (2010)
  39. Wu C, Cho TJ, Xu J, Lee D, Yang B, Zachariah MR, Phys. Rev. E, 81, 011406 (2010)
  40. Schmid G, Nanoparticles: From Theory to Application, 2nd Ed. Wiley, Weinheim (2010).
  41. Fiedler SL, Steven L, Izvekov S, Violi A, Carbon, 45, 1786 (2007)
  42. Saien J, Mozafarvandi M, Daliri S, Norouzi M, J. Chem. Thermodyn., 57, 76 (2013)
  43. Godfrey JC, Slater MJ, Liquid-liquid Extraction Equipment, Wiley, Chichester, UK (1994).
  44. Steiner L, Chem. Eng. Sci., 41, 1979 (1986)
  45. Rahbar A, Azizi Z, Bahmanyar H, Moosavian MA, Can. J. Chem. Eng., 89(3), 508 (2011)
  46. Torab-Mostaedi M, Safdari J, Braz. J. Chem. Eng., 26, 685 (2009)
  47. Treybal RE, Mass Transfer Operations, 3rd Ed. McGraw-Hill, USA (1980).