화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.28, 161-170, August, 2015
DOI10.1016/j.jiec.2015.01.026  Export Citation
Hydrogenation of isoprene over gold supported on CeO2, ZrO2, SiO2 and N.SiO2
Kang Yang, and Chenguang Liu†
  • State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, CNPC, College of Chemical Engineering, China University of Petroleum, No. 66, West Changjiang Road, Huangdao, Qingdao 266580, PR China
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In gold catalysis, the charge state issue is of particular importance but still under debate. In this work, four categories of active site (anionic Au on ZrO2, cationic Au on SiO2, metallic Au on functionalized SiO2 (N-SiO2) and anionic Au with OH groups on CeO2) were prepared. After evaluation, the charge state effect was observed. Negatively charged Au on irreducible monoclinic ZrO2 benefits the selective hydrogenation of isoprene, meaning ‘‘charge sensitive reaction’’ was observed. However, the selectivity is not dependent on different active site. No isopentane was produced under experimental conditions.
Keywords:Gold;Negatively charged Au;Monoclinic ZrO2;Hydrogenation of isoprene;Charge sensitive reaction
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