화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.29, 185-193, September, 2015
DOI10.1016/j.jiec.2015.04.002  Export Citation
Synthesis of novel Brønsted.Lewis acidic ionic liquid catalysts and their catalytic activities in acetalization
Yan Wei, Chen Keke, Zhang Xiaofang, Kuang Yingying, Tang Xiujuan1, and Han Xiaoxiang†
  • Department of Applied Chemistry, Zhejiang Gongshang University, Hangzhou 310035, China
  • 1College of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310035, China
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Ionic liquid catalysts which combine the characters of the Bronsted-Lewis solid acids and the ionic liquid are prepared. The obtained composite materials were well characterized by FT-IR, TGA, 1H NMR, 13C NMR and investigated their performance for acetalization. The acid strength was determined by the Hammett method combined with UV-vis spectroscopy. Response surface methodology (RSM) was applied to optimize the synthesis of benzaldehyde glycol acetal and the effects of various reaction conditions. A Box.Behnken experimental Design (BBD) was employed to search for the optimal yield. The kinetic study for the acetalization was performed under the optimum operating conditions.
Keywords:Bronsted-Lewis acidic ionic liquid;Catalyst;Acetalization;Response surface methodology;Kinetic model
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