Polyurethane-based cation exchange composite membranes:Preparation, characterization and its application in development of ion-selective electrode for detection of copper(II)

Umair Baig; Asif Ali Khan

Journal of Industrial and Engineering Chemistry, Vol.29, 392-399, September, 2015

DOI10.1016/j.jiec.2014.12.045 Export Citation

Polyurethane-based cation exchange composite membranes:Preparation, characterization and its application in development of ion-selective electrode for detection of copper(II)

Umair Baig^{1, 2}, and Asif Ali Khan^{1, 3, †}

¹Analytical and Polymer Research Laboratory, Department of Applied Chemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002, UP, India
²Center of Excellence for Scientific Research Collaboration with MIT, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
³, India

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Polyurethane-cerium(IV) phosphate composite cation exchange membranes were prepared by solution casting method in different stoicheometric ratios of polyurethane and cerium(IV) phosphate. The structure and morphology of the prepared membranes were ascertained by FTIR, SEM, TGA and DTA. The membrane having composition 1:2 (PU: cerium(IV) phosphate) shows best results for ion-exchange capacity, water content, porosity, thickness and swelling. The Cu(II) selective electrode was developed by using this membrane for the determination of Cu(II) in solutions. The accuracy of the procedure has been tested on drinking water samples spiked with known amounts of Cu(II) and results were comparable to those generated by Atomic Absorption Spectrophotometer.

Keywords:Polymer;Composite membranes;Cation exchanger;Cu(II) selective electrode

[References]

Xiuhua Y, Yingfeng M, Yuezhong, ACS Appl. Mater. Interfaces, 5, 1414 (2013)
Hosseini SM, Askari M, Koranian P, Madaeni SS, Moghadassi AR, J. Ind. Eng. Chem., 20(4), 2510 (2014)
Arsalan M, Khan MMA, Rafiuddin, Desalination, 318, 97 (2013)
Chung TS, Jian LY, Li Y, Kulprathipanja S, Prog. Polym. Sci, 32, 483 (2007)
Khan A, Asiri AM, Rub MA, Azum N, Khan AAP, Khan SB, Rahman MM, Khan I, Compos. Pt. B, 45, 1486 (2013)
Norgaard CF, Nielsen UG, Skou EM, Solid State Ion., 213, 76 (2012)
Tripathi BP, Shahi VK, Prog. Polym. Sci, 36, 945 (2011)
Leong JX, Daud WRW, Ghasemi M, Liew KB, Ismail M, Ren. Sust. Ener. Rev., 28, 575 (2013)
Volkov VV, Kravchenko TA, Vyacheslav IR, Rus. Chem. Rev., 82, 465 (2013)
Zuo XT, Yu SL, Shi WX, Desalination, 290, 83 (2012)
Khan AA, Baig U, J. Ind. Eng. Chem., 18(6), 1937 (2012)
Khan AA, Baig U, Desalination, 319, 10 (2013)
Khan AA, Baig U, Desalination, 289, 21 (2012)
Khan AA, Baig U, Khalid M, J. Ind. Eng. Chem., 4, 1226 (2013)
Khan AA, Paquiza L, J. Ind. Eng. Chem., 6, 4261 (2014)
Khan AA, Paquiza L, J. Ind. Eng. Chem., (in press). (2014)
Wang N, Wu C, Cheng Y, Xu T, Int. J. Pharma, 408, 39 (2011)
Faust SD, Aly OM, Adsorption Processes for Water Treatment, Butterworth, London, 1987.
Khan AA, Baig U, Compos. Pt. B, 56, 862 (2014)
Khan AA, Ahmad R, Khan A, Mondal PK, Am. J. Chem., 157, 122 (2011)
Recommendation for publishing manuscripts on ion-selective electrodes (prepared for publication by Guilbault GG), Commission on Analytical Nomenclature, Analytical chemistry Division, IUPAC, Ion-Sel El Rev 1969;1:139.
Jain AK, Singh RP, Bala C, Anal. Lett., 15, 1557 (1982)
Peahkovaskii VV, Melnikova RY, Dzyuva ED. Atlas of Infra red spectra of phosphate, orthophosphate. Moscow: Nauka; 1985.
Umezawa Y, Umezawa K, Sato H, Pure Appl. Chem., 67, 507 (1995)
Singh LP, Bhatnagar JM, Talanta, 64, 313 (2004)
Abbaspour A, Kamyabi MA, Anal. Chim. Acta, 455, 225 (2002)
Mittal SK, Kumar SKA, Gupta N, Kaur S, Kumar S, Anal. Chim. Acta, 585, 161 (2007)
Mashhadizadeh MH, Mostafavi A, Razavi R, Shamsipur M, Sens. Actuators B-Chem., 86, 222 (2002)

[Referenced By]

[1] Xiuhua Y, Yingfeng M, Yuezhong, ACS Appl. Mater. Interfaces, 5, 1414 (2013)

[2] Hosseini SM, Askari M, Koranian P, Madaeni SS, Moghadassi AR, J. Ind. Eng. Chem., 20(4), 2510 (2014)

[3] Arsalan M, Khan MMA, Rafiuddin, Desalination, 318, 97 (2013)

[4] Chung TS, Jian LY, Li Y, Kulprathipanja S, Prog. Polym. Sci, 32, 483 (2007)

[5] Khan A, Asiri AM, Rub MA, Azum N, Khan AAP, Khan SB, Rahman MM, Khan I, Compos. Pt. B, 45, 1486 (2013)

[6] Norgaard CF, Nielsen UG, Skou EM, Solid State Ion., 213, 76 (2012)

[7] Tripathi BP, Shahi VK, Prog. Polym. Sci, 36, 945 (2011)

[8] Leong JX, Daud WRW, Ghasemi M, Liew KB, Ismail M, Ren. Sust. Ener. Rev., 28, 575 (2013)

[9] Volkov VV, Kravchenko TA, Vyacheslav IR, Rus. Chem. Rev., 82, 465 (2013)

[10] Zuo XT, Yu SL, Shi WX, Desalination, 290, 83 (2012)

[11] Khan AA, Baig U, J. Ind. Eng. Chem., 18(6), 1937 (2012)

[12] Khan AA, Baig U, Desalination, 319, 10 (2013)

[13] Khan AA, Baig U, Desalination, 289, 21 (2012)

[14] Khan AA, Baig U, Khalid M, J. Ind. Eng. Chem., 4, 1226 (2013)

[15] Khan AA, Paquiza L, J. Ind. Eng. Chem., 6, 4261 (2014)

[16] Khan AA, Paquiza L, J. Ind. Eng. Chem., (in press). (2014)

[17] Wang N, Wu C, Cheng Y, Xu T, Int. J. Pharma, 408, 39 (2011)

[18] Faust SD, Aly OM, Adsorption Processes for Water Treatment, Butterworth, London, 1987.

[19] Khan AA, Baig U, Compos. Pt. B, 56, 862 (2014)

[20] Khan AA, Ahmad R, Khan A, Mondal PK, Am. J. Chem., 157, 122 (2011)

[21] Recommendation for publishing manuscripts on ion-selective electrodes (prepared for publication by Guilbault GG), Commission on Analytical Nomenclature, Analytical chemistry Division, IUPAC, Ion-Sel El Rev 1969;1:139.

[22] Jain AK, Singh RP, Bala C, Anal. Lett., 15, 1557 (1982)

[23] Peahkovaskii VV, Melnikova RY, Dzyuva ED. Atlas of Infra red spectra of phosphate, orthophosphate. Moscow: Nauka; 1985.

[24] Umezawa Y, Umezawa K, Sato H, Pure Appl. Chem., 67, 507 (1995)

[25] Singh LP, Bhatnagar JM, Talanta, 64, 313 (2004)

[26] Abbaspour A, Kamyabi MA, Anal. Chim. Acta, 455, 225 (2002)

[27] Mittal SK, Kumar SKA, Gupta N, Kaur S, Kumar S, Anal. Chim. Acta, 585, 161 (2007)

[28] Mashhadizadeh MH, Mostafavi A, Razavi R, Shamsipur M, Sens. Actuators B-Chem., 86, 222 (2002)