Solvent extraction of vanadium(V) from sulfate solutions using LIX 63 and PC 88A

Thi Hong Nguyen; Man Seung Lee

Journal of Industrial and Engineering Chemistry, Vol.31, 118-123, November, 2015

DOI10.1016/j.jiec.2015.06.015 Export Citation

Solvent extraction of vanadium(V) from sulfate solutions using LIX 63 and PC 88A

Thi Hong Nguyen, and Man Seung Lee^†

Department of Advanced Material Science and Engineering, Institute of Rare Metal, Mokpo National University, 61 Dorim-ri, Chungye-Myun, Muan-gun, Chonnam 534-729, Republic of Korea

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Extraction of V(V) by LIX 63 and PC 88A was investigated from sulfate solutions under initial pH 1.2-6. Equilibrium pH had a profound effect on the extraction of V(V) by the two extractants. The extraction of V(V) by PC 88A occurred by a cationic exchange, while that by LIX 63 changed as the equilibrium pH increased. The cationic exchange reaction of VO2 + by LIX 63 occurred at pH < 2.5, while solvating reaction occurred in the equilibrium pH range of 2.5-5.4. The extraction reactions of V(V) by PC 88A and LIX 63 were identified by applying a slope method.

Keywords:Vanadium;Sulfate solution;Solvent extraction;LIX 63;PC 88A

[References]

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Naeemullah, Kazi TG, Tuzen M, Food Chem., 172, 161 (2015)
Pekiner OZ, Naeemullah, Tuzen M, J. Ind. Eng. Chem., 20(4), 1825 (2014)
Naeemullah, Tuzen M, Kazi TG, Citak D, Soylak M, J. Anal. Spectrom., 28, 1441 (2013)
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Nguyen TH, Lee MS, Ind. Eng. Chem. Res., 53(20), 8608 (2014)
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Lozano LJ, Juan D, Solvent Extr. Ion Exch., 19, 359 (2001)
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Chagnes A, Rager MN, Courtaud B, Thiry J, Cote G, Hydrometallurgy, 104, 20 (2010)
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Olazabal MA, Orive MM, Fernandez LA, Madariaga JM, Solvent Extr. Ion Exch., 10, 623 (1992)
Nguyen TH, Lee MS, Hydrometallurgy, 155, 51 (2015)
Nakamura S, Ozeki T, J. Chem. Soc.-Dalton Trans., 4, 472 (2001)
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[Referenced By]

[1] Kim HI, Lee KW, Mishra D, Yi KM, Hong JH, Jun MK, Park HK, J. Ind. Eng. Chem., 20(6), 4457 (2014)

[2] El-Nadi YA, Awwad NS, Nayl AA, Int. J. Miner. Process., 90, 115 (2009)

[3] Zeng L, Cheng CY, Hydrometallurgy, 101, 141 (2010)

[4] Zhang P, Inoue K, Yoshizuka K, Tsuyama H, Hydrometallurgy, 41, 45 (1996)

[5] Li W, Zhang Y, Liu T, Huang J, Wang Y, Hydrometallurgy, 131-132, 1 (2013)

[6] Navarro R, Guzman J, Saucedo I, Revilla J, Guibal E, Waste Manage., 27, 425 (2007)

[7] Naeemullah, Kazi TG, Tuzen M, Food Chem., 172, 161 (2015)

[8] Pekiner OZ, Naeemullah, Tuzen M, J. Ind. Eng. Chem., 20(4), 1825 (2014)

[9] Naeemullah, Tuzen M, Kazi TG, Citak D, Soylak M, J. Anal. Spectrom., 28, 1441 (2013)

[10] Li XB, Wei C, Wu J, Li CX, Li MT, Deng ZG, Xu HS, Trans. Nonferrous Met. Soc. China, 22, 461 (2012)

[11] Nguyen TH, Lee MS, Ind. Eng. Chem. Res., 53(20), 8608 (2014)

[12] Nekovar P, Schrotterova D, J. Radioanal. Nucl. Chem., 228, 95 (1998)

[13] Lozano LJ, Juan D, Solvent Extr. Ion Exch., 19, 359 (2001)

[14] Bal YB, Bal KE, Cote G, Lallam A, Hydrometallurgy, 75, 123 (2004)

[15] Chagnes A, Rager MN, Courtaud B, Thiry J, Cote G, Hydrometallurgy, 104, 20 (2010)

[16] Sahu KK, Agrawal A, Mishra D, J. Environ. Manage., 125, 68 (2013)

[17] Li XB, Wei C, Wu J, Li MT, Deng Z, Li CX, Xu HS, Sep. Purif. Technol., 71, 64 (2012)

[18] Earnshaw A, Greenwood N, Chemistry of the Elements, second ed., Elsevier B.V., UK, 1997.

[19] Zeng L, Cheng CY, Hydrometallurgy, 98, 10 (2009)

[20] Olazabal MA, Orive MM, Fernandez LA, Madariaga JM, Solvent Extr. Ion Exch., 10, 623 (1992)

[21] Nguyen TH, Lee MS, Hydrometallurgy, 155, 51 (2015)

[22] Nakamura S, Ozeki T, J. Chem. Soc.-Dalton Trans., 4, 472 (2001)

[23] Day VW, Klemperer WG, Maltbie DJ, J. Am. Chem. Soc., 109, 2991 (1987)

[24] Dewan A, Kakati DK, Das BK, Indian J. Chem., 49, 39 (2010)

[25] Foulon C, Pareau D, Durand G, Hydrometallurgy, 51, 139 (1999)