화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.31, 142-155, November, 2015
DOI10.1016/j.jiec.2015.06.018  Export Citation
The beneficial utilization of natural zeolite in preparation of Cr/clinoptilolite nanocatalyst used in CO2-oxidative dehydrogenation of ethane to ethylene
Farhad Rahmani1, 2, Mohammad Haghighi1, 2, †, and Majed Amini1, 2
  • 1Chemical Engineering Faculty, Sahand University of Technology, PO Box 51335-1996, Sahand New Town, Tabriz, Iran
  • 2Reactor and Catalysis Research Center (RCRC), Sahand University of Technology, PO Box 51335-1996, Sahand New Town, Tabriz, Iran
E-mail:
The oxidative dehydrogenation of ethane in the presence of CO2 was investigated over a series of Crimpregnated clinoptilolite catalysts exploring the natural zeolitic support potential. The as-synthesized nanocatalysts were characterized by XRD, BET, FESEM, TEM, ICP, FTIR, EDX and TPD-NH3 techniques. It was found that Cr supported on the acid treated clinoptilolite followed by NH4NO3 treatment nanocatalyst effectively dehydrogenated ethane to ethylene in the presence of CO2 at 700 °C, giving 39.3 and 98.8% ethylene yield and selectivity, respectively. A promoting effect of CO2 on the ethane dehydrogenation over the most active catalyst was also observed.
Keywords:Natural zeolite;Cr/clinoptilolite;Dehydrogenation;Ethane;Ethylene
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