Santolina chamaecyparissus extract as a natural source inhibitor for 304 stainless steel corrosion in 3.5% NaCl

M. Shabani-Nooshabadi; M.S. Ghandchi

Journal of Industrial and Engineering Chemistry, Vol.31, 231-237, November, 2015

DOI10.1016/j.jiec.2015.06.028 Export Citation

Santolina chamaecyparissus extract as a natural source inhibitor for 304 stainless steel corrosion in 3.5% NaCl

M. Shabani-Nooshabadi^†, and M.S. Ghandchi

Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Islamic Republic of Iran

E-mail:

The inhibitive action of Santolina chamaecyparissus extract as a natural inhibitor on corrosion of 304 stainless steel in 3.5% NaCl solution was investigated by potentiodynamic polarization, EIS, and SEM techniques. The results indicate that the extract shows mixed-type inhibition behavior and inhibition efficiency of 86.9% was achieved with the addition of 1.0 gL -1 extract. Impedance curves show that increasing Santolina concentration increases charge transfer resistance and decreases double layer capacitance. The corrosion rate decreased with increasing concentration of extract and increased with the increase in temperature of the medium. Adsorption of the extract obeyed the Langmuir isotherm model.

Keywords:Corrosion;304 stainless steel;Green inhibitor;Polarization;EIS;3.5% NaCl solution

[References]

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[Referenced By]

[1] Wang D, Bierwagen GP, Prog. Inorg. Coat., 64, 327 (2009)

[2] Fedrizzi L, Rodriguez FJ, Rossi S, Deflorian F, Di Maggio R, Electrochim. Acta, 46(24-25), 3715 (2001)

[3] Masalski J, Gluszek J, Zabrzeski J, Nitsch K, Gluszek P, Thin Solid Films, 349(1-2), 186 (1999)

[4] Pardo A, Merino MC, Coy AE, Viejo F, Arrabal R, Matykina E, Corrosion Sci., 50, 780 (2008)

[5] Burstein GT, Souto RM, Liu C, Vines SP, Corros. Mater., 29, S1 (2004)

[6] Burstein GT, Pistorius PC, Mattin SP, Corrosion Sci., 35, 57 (1993)

[7] Frankel GS, Sridhar N, Mater. Today, 11, 38 (2008)

[8] Abdel-Gaber AM, Abd-El-Nabey BA, Saadawy M, Corrosion Sci., 51, 1038 (2009)

[9] Oguzie EE, Corrosion Sci., 50, 2993 (2008)

[10] Gerengi H, Schaefer K, Sahin HI, J. Ind. Eng. Chem., 18(6), 2204 (2012)

[11] Behpour M, Ghoreishi SM, KhayatKashani M, Soltani N, Mater. Corros., 60, 895 (2009)

[12] El-Etre AY, Corrosion Sci., 45, 2485 (2003)

[13] Abdel-Gaber AM, Abd-El-Nabey BA, Sidahmad IM, El-Zayady AM, Saadawy M, Corrosion Sci., 48, 2765 (2005)

[14] El-Etre AY, Appl. Surf. Sci., 252(24), 8521 (2006)

[15] Noor EA, J. Appl. Electrochem., 39(9), 1465 (2009)

[16] Eddy NO, Odoemelam SA, Odiongenyi AO, J. Appl. Electrochem., 39(6), 849 (2009)

[17] Rahim AA, Rocca E, Steinmetz J, Kassim MJ, Adnan R, Ibrahim MS, Corrosion Sci., 49, 402 (2007)

[18] Martinez S, Stern I, Appl. Surf. Sci., 199(1-4), 83 (2002)

[19] Bouyanzer A, Hammouti B, Majidi L, Mater. Lett., 60, 2840 (2006)

[20] Quraishi MA, Singh A, Singh VK, Yadav DK, Singh AK, Mater. Chem. Phys., 122(1), 114 (2010)

[21] Behpour M, Ghoreishi SM, Khayatkashani M, Soltani N, Mater. Chem. Phys., 131(3), 621 (2012)

[22] Lebrini M, Robert F, Lecante A, Roos C, Corrosion Sci., 53, 687 (2011)

[23] Okafor PC, Ikpi ME, Uwaha IE, Ebenso EE, Ekpe UJ, Umoren SA, Corrosion Sci., 50, 2310 (2008)

[24] Shabani-Nooshabadi M, Hoseiny FS, Jafari Y, Anal. Biochem., 6, 341 (2014)

[25] Shabani-Nooshabadi M, Hoseiny FS, Jafari Y, Metall. Mater. Trans., 46, 293 (2015)

[26] Vathsala K, Venkatesha TV, Appl. Surf. Sci., 257(21), 8929 (2011)

[27] Shubha HN, Venkatesha TV, Vathsala K, Pavitra MK, Kumar MKP, ACS Appl. Mater. Interfaces, 5, 10738 (2013)

[28] Mansfeld F, Corrosion Sci., 47, 3178 (2005)

[29] McCafferty E, Corrosion Sci., 47, 3202 (2005)

[30] Martinez S, Metikos-Hukovic M, J. Appl. Electrochem., 33(12), 1137 (2003)

[31] Fu JJ, Zang HS, Wang Y, Li SN, Chen T, Liu XD, Ind. Eng. Chem. Res., 51(18), 6377 (2012)

[32] Hu JM, Liu XL, Zhang JQ, Cao CN, Prog. Org. Coat., 55, 388 (2006)

[33] Shimizu K, Lasia A, Boily JF, Langmuir, 28(20), 7914 (2012)

[34] Motamedi M, Tehrani-Bagha AR, Mandavian M, Electrochim. Acta, 58, 488 (2011)

[35] Agarwal P, Orazem ME, Garcia-Rubio LH, J. Electrochem. Soc., 139, 1917 (1992)

[36] Pavithra MK, Venkatesha TV, Vathsala K, Nayana KO, Corrosion Sci., 52, 3811 (2010)

[37] Outirite M, Lagrenee M, Lebrini M, Traisnel M, Jama C, Vezin H, Bentiss F, Electrochim. Acta, 55(5), 1670 (2010)

[38] Ivanov ES, Inhibitors for Metal Corrosion in Acid Media, Metallurgy, Moscow, 1986.

[39] Noor EA, Al-Moubaraki AH, Mater. Chem. Phys., 110(1), 145 (2008)

[40] Wu XJ, Ma HY, Chen SH, Xu ZY, Sui AF, J. Electrochem. Soc., 146(5), 1847 (1999)

[41] Khaled KF, Hackerman N, Electrochim. Acta, 48(19), 2715 (2003)

[42] Gurudatt DM, Mohana KN, Ind. Eng. Chem. Res., 53(6), 2092 (2014)

[43] Teresa JD, Bellido IS, Gonzalez MS, Vicente S, Phytochemistry, 25, 185 (1985)

[44] Barrero AF, Alvarez-Manzaneda R, Quilez JF, Herrador MM, Phytochemistry, 48, 807 (1998)