Kinetic study of the adsorption of textile dyes on synthetic hydroxyapatite in aqueous solution

W. Lemlikchi; N. Drouiche; N. Belaicha; N. Oubagha; B. Baaziz; M.O. Mecherri

Journal of Industrial and Engineering Chemistry, Vol.32, 233-237, December, 2015

DOI10.1016/j.jiec.2015.08.023 Export Citation

Kinetic study of the adsorption of textile dyes on synthetic hydroxyapatite in aqueous solution

W. Lemlikchi, N. Drouiche^{1, †}, N. Belaicha, N. Oubagha, B. Baaziz, and M.O. Mecherri

Laboratoire LCAGC, Universite Mouloud Mammeri, Tizi-Ouzou 15000, Algeria
¹Centre de Recherche en technologie des Semi-conducteurs pour l’Energetique (CRTSE), 2, Bd Frantz Fanon BP140, Alger – 7 merveilles, 16038, Algeria

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Textile mill effluent present a high pollution potential and health risk. These effluents require prior treatment before being discharged back into the environment. The objective of this study was to eliminate three textile dyes viz. the Blue Hydron (HB), the Blue Solophenyl (SB) and the Turquoise Solophenyl (ST) by adsorption vs. Co-precipitation on hydroxyapatite (HAP) in batch mode at neutral pH and room temperature. Structural and morphological characterization was performed using FTIR and SEM analyses. The results show that the adsorption capacity is higher for the Hydron Blue (HB) compared to Solophenyl Blue (SB) which is lower than the adsorption capacity of Solophenyl Turquoise (ST). The equilibrium data fit well to the Freundlich isotherm.

Keywords:Adsorption;Decolorization;Textile dyes;Textile mill effluent;Synthetic hydroxyapatite

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Barka N, Qourzal S, Assabbane A, Nounah A, Ait-ichou Y, J. Environ. Sci., 20, 1268 (2008)
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[1] Uddin MT, Islam MA, Mahmud S, Rukanuzzaman M, J. Hazard. Mater., 164(1), 53 (2009)

[2] Grassi M, Kaykioglu G, Belgiorno V, Lofrano G, Emerging Compounds removal from Wastewater. Springer Briefs in Green Chemistry for Sustainability, vol. 10, 2012, p. 978.

[3] Lambert SD, Graham NJD, Sollars CJ, Fowler GD, Water Sci. Technol., 36, 173 (1997)

[4] Hadioui M, Synthe` se d’hydroxyapatite et de silices greffe´ es pour l’e´ limination de me´taux toxiques en solution aqueuse, Universite´ Paul Sabatier Toulouse III, 2007 (These Doctorat).

[5] Reddy MP, Venugopal A, Subrahmanyam M, Appl. Catal. B: Environ., 69(3-4), 164 (2007)

[6] Barka N, Qourzal S, Assabbane A, Nounah A, Ait-ichou Y, J. Environ. Sci., 20, 1268 (2008)

[7] Lemlikchi W, Sharrock P, Mecherri MO, Fiallo M, Int. J. Mater. Eng. Technol., 6, 111 (2011)

[8] Lemlikchi W, Sharrock P, Fiallo M, Nzihou A, Mecherri MO, Proc. Eng., 83, 378 (2014)

[9] Lemlikchi W, Elimination de la pollution des eaux industrielles par diffe´ rents proce´des d’oxydation et de co-pre´ cipitation, Universite´ Tizi-Ouzou UMMTO Algeria, 2012 (The` se Doctorat).

[10] Gilles GH, Evant MCM, Nakhawas SW, Smith DJ, J. Chem. Soc., 3973 (1960)

[11] Lemlikchi W, Sharrock P, Mecherri MO, Fiallo M, Nzihou A, Waste Biomass Valoriz., 3, 75 (2012)

[12] Lemlikchi W, Sharrock P, Mecherri MO, Fiallo M, Nzihou A, Des. Water Treat., 52, 669 (2014)

[13] Noreen S, Bhatti HN, J. Ind. Eng. Chem., 20(4), 1684 (2014)

[14] Kadouche S, Zemmouri H, Benaoumeur K, Drouiche N, Sharrock P, Lounici H, Proc. Eng., 33, 377 (2012)

[15] Kadouche S, Lounici H, Benaoumeur K, Drouiche N, Hadioui M, Sharrock P, J. Polym. Environ., 20, 848 (2012)

[16] Sadaf S, Bhatti HN, ana Nausheen S, Amin M, J. Taiwan Inst. Chem. Eng., 47, 160 (2015)

[17] Lemlikchi W, Drouiche N, Baaziz B, Mecherri MO, Sep. Sci. Technol., http://dx.doi.org/10.1080/01496395.2015.1071850. (2015)