화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.32, 313-318, December, 2015
DOI10.1016/j.jiec.2015.09.015  Export Citation
Hydrothermal synthesis of morphology controllable Cu2O and their catalysis in thermal decomposition of ammonium perchlorate
Xiao-Lin Luo1, 2, Min-Juan Wang2, De-Suo Yang2, Jie Yang1, 3, and Ya-Shao Chen1, 3, †
  • 1Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi’an 710062, PR China
  • 2Shaanxi Key Laboratory for Phytochemistry, Chemistry & Chemistry Engineering Department, Baoji University of Arts and Sciences, Baoji 721001, PR China
  • 3, China
E-mail:
Cu2O micro-crystals with different morphologies (including three branching structures) were synthesized through hydrothermal method by using sodium tartrate as chelating reagent. Branching growth patterns of Cu2O microcrystals have a strong dependence on the amount of sodium tartrate. These different Cu2O microcrystals were used as catalysts to promote the thermal decomposition of ammonium perchlorate (AP). The thermal decomposition of AP in the presence or absence of Cu2O micro-crystals was investigated non-isothermally through thermogravimetry and differential scanning calorimetry (DSC). The data obtained from DSC were applied for the calculation and comparison of the kinetic parameters of AP decomposition process through a model-free approach.
Keywords:Cu2O;Hydrothermal synthesis;Catalysis;Kinetics
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