Analytical pyrolysis properties of waste medium-density fiberboard and particle board

Tae Uk Han; Young-Min Kim; Chuichi Watanabe; Norio Teramae; Young-Kwon Park; Seungdo Kim; Yunhee Lee

Journal of Industrial and Engineering Chemistry, Vol.32, 345-352, December, 2015

DOI10.1016/j.jiec.2015.09.008 Export Citation

Analytical pyrolysis properties of waste medium-density fiberboard and particle board

Tae Uk Han¹, Young-Min Kim^{1, 2}, Chuichi Watanabe^{1, 3}, Norio Teramae^{1, 4}, Young-Kwon Park⁵, Seungdo Kim^{1, †}, and Yunhee Lee¹

¹Department of Environmental Sciences and Biotechnology, Hallym University, Chuncheon 200-702, Republic of Korea
²Frontier Laboratories Ltd., 1-8-14, Saikon, Koriyama, Fukushima 963-8862, Japan
³, Korea
⁴Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan
⁵School of Environmental Engineering, University of Seoul, Seoul 130-743, Republic of Korea

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Medium-density fiberboard (MDF) and particle board (PB) showed similar pyrolysis characteristics. Thermogravimetric analysis displayed the main weight loss between 200 and 400 ℃, continued up to 600 ℃. The activation energy (Ea) values at each conversion were in the range of 166.372 kJ/mol for MDF and 161.325 kJ/mol for PB and indicated independent reactions of hemicellulose, cellulose, lignin and char stabilization. Isothermal pyrolysis produced hemicellulose pyrolyzates at 300 ℃. The main products at 400 8C had similar distribution between MDF and PB. At 600 ℃, gas products were increased due to the secondary cracking of pyrolyzates.

Keywords:Medium-density fiberboard;Particle board;TGA;EGA-MS;Py-GC/MS

[References]

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Gu X, Ma X, Li L, Liu G, Cheng K, Li Z, J. Anal. Appl. Pyrolysis, 102, 16 (2013)
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Park YK, Choi S, Jeon J, Park S, Ryoo R, Kim J, Jeong K, J. Nanosci. Nanotechnol., 12, 5367 (2012)
Kim JW, Lee HW, Lee IG, Jeon JK, Ryu C, Park SH, Jung SC, Park YK, Renew. Energy, 65, 41 (2014)
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[11] Kim SD, Park JK, Thermochim. Acta, 264, 137 (1995)

[12] Telmo C, Lousada J, Moreira N, Bioresour. Technol., 101(11), 3808 (2010)

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[16] Dutta S, Pal S, Biomass Bioenerg., 62, 182 (2014)

[17] Wu Y, Zhao Z, Li L, He F, J. Fuel Chem. Technol., 37, 427 (2009)

[18] Shen DK, Gu S, Luo KH, Wang SR, Fang MX, Bioresour. Technol., 101(15), 6136 (2010)

[19] Pandey MP, Kim CS, Chem. Eng. Technol., 34(1), 29 (2011)

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[21] Stefanidis SD, Kalogiannis KG, Iliopoulou EF, Michailof CM, Pilavachi PA, Lappas AA, J. Anal. Appl. Pyrolysis, 105, 143 (2014)

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[28] Shen DK, Bridgwater AV, J. Anal. Appl. Pyrolysis, 87, 199 (2010)

[29] Bridgwater AV, J. Anal. Appl. Pyrolysis, 51, 3 (1999)

[30] Bridgwater AV, Meier D, Radlein D, Org. Geochem., 30, 1479 (1999)