화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.33, No.1, 132-139, January, 2016
DOI10.1007/s11814-015-0109-8  Export Citation
Deep extractive desulfurization of oil over 12-Molibdophosphoric acid encapsulated in metal-organic frameworks
Ezzat Rafiee1, 2, †, and Narges Nobakht2
  • 1Faculty of Chemistry, Razi University, Kermanshah 67149, Iran
  • 2Institute of Nano Science and Nano Technology, Razi University, Kermanshah 67149, Iran
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A desulfurization process for model oil and real oil was investigated based on the chemical oxidation of mixed sulfur containing compounds in the presence of nitrogen compounds (indole and quinoline) using hydrogen peroxide as oxidizing agent and dodecamolibdophosphoric acid (H3PMo12O40) encapsulated in a kind of metal-organic framework (HKUST-1) as PMo@HKUST-1. The effect of isopropanol, ethanol and acetonitrile as extractive solvent and 1-ring (toluene, xylene and mesitylene) and 2-ring (naphthalene) aromatic hydrocarbons in desulfurization of model oil was studied. The desulfurization of sulfur-containing compounds was accelerated in the presence of aromatic hydrocarbons. In fact, a higher desulfurization efficiency of the heterogeneous catalyst could be achieved with system containing a polar solvent in contact with an aromatic hydrocarbon. Quinoline had no effect on oxidative desulfurization (ODS) reaction, whereas indole had a slightly negative effect. Presence of aromatic compounds had slightly positive effect on ODS reaction.
Keywords:Oxidative Desulfurization;Real Oil;Polyoxometalates;Metal-organic Frameworks
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