화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.33, No.1, 319-329, January, 2016
DOI10.1007/s11814-015-0102-2  Export Citation
Synthesis and characterization of polyhedral oligomeric silsesquioxane-based waterborne polyurethane nanocomposites
Hengameh Honarkar, Mohammad Barmar†, Mehdi Barikani, and Parvin Shokrollahi1
  • Polyurethane and Advanced Polymers Department, Faculty of Science, Iran Polymer and Petrochemical Institute, Tehran, Iran
  • 1Biocompatible Polymers Department, Faculty of Science, Iran Polymer and Petrochemical Institute, Tehran, Iran
E-mail:
A series of aqueous polyurethane nanocomposites were prepared using various amounts (0.3-4.6 wt%) of a diol functionalized polyhedral oligomeric silsesquioxane (POSS) by the prepolymer mixing method. N,N-bis(2-hydroxy ethyl-2-amino ethane sulfonic acid sodium salt (BES sodium salt) was used as the anionic internal emulsifier and ionic center. The molecular structure of the samples was characterized by ATR-FTIR spectroscopy. We investigated the effect of the POSS contents on the properties of the specimens by particle size and viscosity measurements, X-ray diffractometry, mechanical behavior assessment, dynamic mechanical thermal analysis (DMTA), thermogravimetric analysis and morphological studies. The results showed that with increasing the POSS contents, particle size, viscosity, tensile strength, modulus, Tg, and thermal stability of the synthesized samples were improved. Also, SEM and TEM images indicated that a homogeneous morphology was obtained in the 1.2 wt% POSS-based sample. AFM results showed that the surface roughness increased as the POSS amounts increased.
Keywords:Nanocomposites;Aqueous Polyurethane;POSS;Anionic;Emulsifier
  1. Raftopoulos KN, Pielichowski K, Prog. Polym. Sci, In Press (2015)
  2. Kuo SW, Chang FC, Prog. Polym. Sci, 36, 1649 (2011)
  3. Cordes DB, Lickiss PD, Rataboul F, Chem. Rev., 110(4), 2081 (2010)
  4. Pielichowski K, Njuguna J, Janowski B, Pielichowski J, Adv. Polym. Sci., 201, 225 (2006)
  5. Sanchez C, de A. A. Soler-Illia GJ, Ribot F, Lalot T, Mayer CR, Cabuil V, Chem. Mater., 13, 3061 (2001)
  6. Neumann D, Fisher M, Tran L, Matisons JG, J. Am. Chem. Soc., 124(47), 13998 (2002)
  7. Yadav SK, Mahapatra SS, Ryu HJ, Yoo HJ, Cho JW, React. Funct. Polym., 81, 91 (2014)
  8. Fina A, Tabuani D, Camino G, Eur. Polym. J., 46, 14 (2010)
  9. Feng Y, Jia Y, Guang SY, Xu HY, J. Appl. Polym. Sci., 115(4), 2212 (2010)
  10. Cozza ES, Monticelli O, Marsano E, Macromol. Mater. Eng., 295, 791 (2010)
  11. Ricco L, Russo S, Monticelli O, Bordo A, Bellucci F, Polymer, 46(18), 6810 (2005)
  12. Misra R, Cook RD, Morgan SE, J. Appl. Polym. Sci., 115(4), 2322 (2010)
  13. Iyer P, Iyer G, Coleman M, J. Membr. Sci., 358(1-2), 26 (2010)
  14. Zhang Z, Liang G, Wang J, Ren P, Polym. Compos., 28, 175 (2007)
  15. Soong SY, Cohen RE, Boyce MC, Polymer, 48(5), 1410 (2007)
  16. Kopesky ET, McKinley GH, Cohen RE, Polymer, 47(1), 299 (2006)
  17. Zhao YQ, Schiraldi DA, Polymer, 46(25), 11640 (2005)
  18. Zhang HJ, Kulkarni S, Wunder SL, J. Phys. Chem. B, 111(14), 3583 (2007)
  19. Wang ZB, Leng SW, Wang ZG, Li GY, Yu H, Macromolecules, 44(3), 566 (2011)
  20. Wang Z, Wang Z, Yu H, Zhao L, Qu J, RSC Adv., 2, 2759 (2012)
  21. Zhou ZY, Yin NW, Zhang Y, Zhang YX, J. Appl. Polym. Sci., 107(2), 825 (2008)
  22. Song L, Xuan SY, Wang X, Hu Y, Thermochim. Acta, 527, 1 (2012)
  23. Liu L, Hu Y, Song L, Gu X, Ni Z, Iran. Polym. J., 19, 937 (2010)
  24. Jeziorska R, Swierz-Motysia B, Szadkowska A, Marciniec B, Maciejewski H, Dutkiewicz M, Leszczynska I, Polimery, 56, 809 (2011)
  25. Tegou E, Bellas V, Gogolides E, Argitis P, Microelectron. Eng., 73-74, 238 (2004)
  26. Fiayyaz M, Zia KM, Zuber M, Jamil T, Khosa MK, Jamal MA, Korean J. Chem. Eng., 31(4), 644 (2014)
  27. Zuber M, Zia KM, Iqbal MA, Cheema ZT, Ishaq M, Jamil T, Korean J. Chem. Eng., 32(1), 184 (2015)
  28. Zhang QH, Huang X, Wang XH, Jia XD, Xi K, Polymer, 55(5), 1282 (2014)
  29. Gnanasekaran D, Reddy BS, Polym. Int., 63, 507 (2014)
  30. Lewicki JP, Pielichowski K, Jancia M, Hebda E, Albo RLF, Maxwell RS, Polym. Degrad. Stabil., 104, 50 (2014)
  31. Przadka D, Jeczalik J, Andrzejewska E, Marciniec B, Dutkiewicz M, Szlapka M, React. Funct. Polym., 73(1), 114 (2013)
  32. Solouk A, Solati-Hashjin M, Najarian S, Mirzadeh H, Seifalian AM, Iran Polym. J., 20, 91 (2011)
  33. Janowski B, Pielichowski K, Thermochim. Acta, 478(1-2), 51 (2008)
  34. Barikani M, Honarkar H, Barikani M, Monatsh. Chem., 141, 653 (2010)
  35. Mumtaz F, Zuber M, Zia KM, Jamil T, Hussain R, Korean J. Chem. Eng., 30(12), 2259 (2013)
  36. Sultan M, Bhatti HN, Zuber M, Barikani M, Korean J. Chem. Eng., 30(2), 488 (2013)
  37. Nanda AK, Wicks DA, Madbouly SA, Otaigbe JU, Macromolecules, 39(20), 7037 (2006)
  38. Turri S, Levi M, Macromol. Rapid Commun., 26(15), 1233 (2005)
  39. Wang X, Hu Y, Song L, Xing W, Lu H, Lv P, Jie G, J. Polym. Res., 18, 721 (2011)
  40. Lewandowski K, Krepski LR, Mickus DE, Roberts RR, Heilmann SM, Larson WK, Purgett MD, Koecher SD, Johnson SA, McGurran DJ, Rueb CJ, Pathre SV, Thakur KAM, J. Polym. Sci. A: Polym. Chem., 40(17), 3037 (2002)
  41. Socrates G, Infrared and raman characteristic group frequencies, 3rd Ed., Wiley, London (2004).
  42. Lee HT, Wu SY, Jeng RJ, Colloids Surf. A: Physicochem. Eng. Asp., 276, 176 (2006)
  43. Barni A, Levi M, J. Appl. Polym. Sci., 88(3), 716 (2003)
  44. Fu BX, Zhang W, Hsiao BS, Rafailovich M, Sokolov J, Johansson G, Sauer BB, Phillips S, Balnski R, High Perform. Polym., 12, 565 (2000)
  45. Hepburn C, Polyurethane elastomers, Applied Science, England (1982).
  46. Zheng L, Farris RJ, Coughlin EB, Macromolecules, 34(23), 8034 (2001)
  47. Xu HY, Kuo SW, Lee JS, Chang FC, Macromolecules, 35(23), 8788 (2002)
  48. Lu MG, Lee JY, Shim MJ, Kim SW, J. Appl. Polym. Sci., 85(12), 2552 (2002)
  49. Grassie N, Scott G, Polymer degradation and stabilisation, Cambridge University, London (1985).
  50. Liu HZ, Zheng SX, Macromol. Rapid Commun., 26(3), 196 (2005)
  51. Zhang S, Zou Q, Wu L, Macromol. Mater. Eng., 291, 895 (2006)
  52. Kourkoutsaki T, Logakis E, Kroutilova I, Matejka L, Nedbal J, Pissis P, J. Appl. Polym. Sci., 113(4), 2569 (2009)
  53. Zhang WH, Fu BX, Seo Y, Schrag E, Hsiao B, Mather PT, Yang NL, Xu DY, Ade H, Rafailovich M, Sokolov J, Macromolecules, 35(21), 8029 (2002)
  54. Dong WP, Sullivan PJ, Stout KJ, Wear, 178, 29 (1994)
  55. Aneja A, Wilkes GL, Polymer, 44(23), 7221 (2003)
  56. Bliznyuk VN, Tereshchenko TA, Gumenna MA, Gomza YP, Shevchuk AV, Klimenko NS, Shevchenko VV, Polymer, 49(9), 2298 (2008)