Preparation of hypercrosslinked poly(DVB-VBC) particles with high surface area and structured meso- and micropores

Ki Seob Hwang; Won Jun Choi; Jung-Hyun Kim; Jun-Young Lee

Macromolecular Research, Vol.23, No.11, 1051-1058, November, 2015

DOI10.1007/s13233-015-3137-7 Export Citation

Preparation of hypercrosslinked poly(DVB-VBC) particles with high surface area and structured meso- and micropores

Ki Seob Hwang, Won Jun Choi¹, Jung-Hyun Kim¹, and Jun-Young Lee^†

Korea Institute of Industrial Technology, 89 Yangdaegiro-gil, Ipjang-myeon, Seobuk-gu, Cheonan-si, Chungnam, 331-822, Korea
¹Department of Chemical Engineering, Yonsei University, 134 Shinchon-Dong, Seodaemoon-Gu, Seoul, 120-749, Korea

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Spherical porous polymer particles with high surface area were synthesized using the water-in-oil-inwater (W/O/W) emulsion polymerization and Friedel-Crafts reaction. After the preparation of W/O emulsions, spherical porous polymer particles were synthesized by suspension polymerization. Spherical porous polymer precursor particles were subjected to Friedel-Crafts reaction using a Lewis acid catalyst. The properties of the final products synthesized with different porogen contents in the water-in-oil (W/O) emulsion were explored. The Friedel-Crafts reaction was used to increase the Brunauer-Emmett-Teller (BET) surface area. In order to identify the effects of the porogen levels and of the Friedel-Crafts reaction, the synthesized porous particles were analyzed by particle size analyzer (PSA), Hg porosimetry, and the BET surface area method. In addition, the morphology of the particles was investigated by FE-SEM.

Keywords:mesoporous;microporous;W/O/W emulsion;porous polymer;high surface area;Friedel-Crafts reaction

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[2] Wu JS, Pisula W, Mullen K, Chem. Rev., 107(3), 718 (2007)

[3] Morris RE, Wheatley PS, Angew. Chem.-Int. Edit., 47, 4966 (2008)

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[7] Nanjangud SC, Brezny R, Green DJ, J. Am. Ceram. Soc., 78, 266 (1995)

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[9] Froen JC, Peffer LAA, Moulijn JA, P-Ramirez J, Microporous Mesoporous Mater., 69, 29 (2004)

[10] Liu JW, Stace-Naughton A, Jiang XM, Brinker CJ, J. Am. Chem. Soc., 131(4), 1354 (2009)

[11] Li Q, Retsch M, Wang J, Knoll W, Jonas UT, Curr. Chem., 287, 135 (2009)

[12] Holst JR, Cooper AI, Adv. Mater., 22 (2010)

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[14] Tsyurupa MP, Davankov VA, React. Funct. Polym., 66(7), 768 (2006)

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