Superior adsorption and photodegradation of eriochrome black-T dye by Fe3+ and Pt4+ impregnated TiO2 nanostructures of different shapes

Bonamali Pal; Rupinder Kaur; Inderpreet Singh Grover

Journal of Industrial and Engineering Chemistry, Vol.33, 178-184, January, 2016

DOI10.1016/j.jiec.2015.09.033 Export Citation

Superior adsorption and photodegradation of eriochrome black-T dye by Fe3+ and Pt4+ impregnated TiO2 nanostructures of different shapes

Bonamali Pal^†, Rupinder Kaur, and Inderpreet Singh Grover

School of Chemistry and Biochemistry, Thapar University, Patiala 147004, Punjab, India

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This article highlights comparative adsorption behavior and photocatalytic activity of TiO2 nanostructures (P25, nanorods and nanotubes) for degradation of eriochrome black-T dye (EBT) depending on their structural morphology and metal ions (Fe3+ and Pt4+) deposition. Enhancement in adsorption capacity (qmax) was observed due to impartment of extra positive charges by Fe3+ and Pt4+ impregnation and follow the order, Pt4+ -P25-TiO2 (400 mg/mg) > Fe3+ -P25-TiO2 (344 mg/mg) > P25-TiO2 (248 mg/mg) > nanotubes (123 mg/mg) > nanorods (69 mg/mg). The Fe3+ and Pt4+ loaded TiO2 improved dye adsorption and degradation rate of EBT undergoing complete minerization to CO2 under UV light irradiation.

Keywords:Metal-TiO2 nanostructures;Fe3+ and Pt4+ loaded TiO2;Dye adsorption isotherm;Ionic surface-dye interaction;Eriochrome black-T degradation

[References]

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Bao Y, Zhang G, Energy Procedia., 16, 1141 (2012)
Namasivayam C, Kavitha D, Dyes Pigment., 54, 47 (2002)
Zaker Y, Hossain MA, Islam TSA, Bangladesh Int. Res. J. Environ. Sci., 2, 1 (2013)
Hameed BH, Ahmad AA, Aziz N, Chem. Eng. J., 133(1-3), 195 (2007)
Kannan N, Sundaram MM, Dyes Pigment., 51, 25 (2001)
Kaur R, Pal B, Mater. Chem. Phys., 143(1), 393 (2013)
Khataee AR, Pons MN, Zahraa O, J. Hazard. Mater., 168(1), 451 (2009)
Wang XH, Li JG, Kamiyama H, Moriyoshi Y, Ishigaki T, J. Phys. Chem. B, 110, 6804 (2006)
Choi W, Hong SJ, Chang YS, Cho Y, Environ. Sci. Technol., 34, 4810 (2000)
Liu G, Wang L, Yang HG, Cheng HM, Lu GQ, J. Mater. Chem., 20, 831 (2010)
Escoto JLV, Chiang YD, Wu KCW, Yamauchi Y, Sci. Technol. Adv. Mater., 13, 1 (2013)
Macwan DP, Dave PN, Chaturvedi S, J. Mater. Sci., 46(11), 3669 (2011)
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Zhu HY, Gao XP, Lan Y, Song DY, Xi YX, Zhao JC, J. Am. Chem. Soc., 126(27), 8380 (2004)
Grover IS, Singh S, Pal B, Appl. Surf. Sci., 280, 366 (2013)
Liao DL, Liao BQ, J. Photochem. Photobiol. A-Chem., 187, 363 (2007)
Jitputti J, Pavasupree S, Suzuki Y, Yoshikawa S, ECS Trans., 16, 3 (2009)
Kansal SK, Sood S, Umar A, Mehta SK, J. Alloy. Compd., 581, 392 (2013)
Kalpagam S, Kannadasan T, J. Chem. Biol. Phys. Sci., 4, 1936 (2014)
Farbod M, Kajbafvala M, Powder Technol., 239, 434 (2013)
Singla P, Sharma M, Pandey OP, Singh K, Appl. Phys. A-Mater. Sci. Process., 116, 371 (2014)
Mamba G, Mbianda XY, Mishra AK, Mater. Chem. Phys., 149-150, 734 (2015)
Ali Z, Chaudhry MN, Hussain ST, Batool SA, Abbas SM, Ahmad N, Ali N, Niaz NA, Dig. J. Nanomater. Bios., 8, 1271 (2013)
Bavykin DV, Redmond KE, Nias BP, Kulak AN, Walsh FC, Aust. J. Chem., 63, 270 (2010)
Kaur R, Pal B, J. Mol. Catal. A-Chem., 355, 39 (2012)
Kamat PV, J. Phys. Chem. B, 106(32), 7729 (2002)
Gupta N, Pal B, J. Mol. Catal. A-Chem., 371, 48 (2013)
Tsai WT, Chang CY, Lin MC, Chien SF, Sun HF, Hsieh MF, Chemosphere, 45, 51 (2001)
Guillard C, Lachheb H, Houas A, Ksibi M, Elaloui E, Herrmann JM, J. Photochem. Photobiol. A-Chem., 158, 27 (2003)
Wong YC, Szeto YS, Cheung WH, McKay G, Process Biochem., 39, 693 (2004)
Dada AO, Olalekan AP, Olatunya AM, Dada O, IOSR J. Appl. Chem., 3, 38 (2012)
Noguchi T, Fujishima A, Environ. Sci. Technol., 32, 3831 (1998)
Kesselman JM, Lewis NS, Hoffmann MR, Environ. Sci. Technol., 31, 2298 (1997)

[Referenced By]

[1] Ong ST, Lee WN, Keng PS, Lee SL, Hung YT, Ha ST, Int. J. Phys. Sci., 5, 582 (2010)

[2] Bao Y, Zhang G, Energy Procedia., 16, 1141 (2012)

[3] Namasivayam C, Kavitha D, Dyes Pigment., 54, 47 (2002)

[4] Zaker Y, Hossain MA, Islam TSA, Bangladesh Int. Res. J. Environ. Sci., 2, 1 (2013)

[5] Hameed BH, Ahmad AA, Aziz N, Chem. Eng. J., 133(1-3), 195 (2007)

[6] Kannan N, Sundaram MM, Dyes Pigment., 51, 25 (2001)

[7] Kaur R, Pal B, Mater. Chem. Phys., 143(1), 393 (2013)

[8] Khataee AR, Pons MN, Zahraa O, J. Hazard. Mater., 168(1), 451 (2009)

[9] Wang XH, Li JG, Kamiyama H, Moriyoshi Y, Ishigaki T, J. Phys. Chem. B, 110, 6804 (2006)

[10] Choi W, Hong SJ, Chang YS, Cho Y, Environ. Sci. Technol., 34, 4810 (2000)

[11] Liu G, Wang L, Yang HG, Cheng HM, Lu GQ, J. Mater. Chem., 20, 831 (2010)

[12] Escoto JLV, Chiang YD, Wu KCW, Yamauchi Y, Sci. Technol. Adv. Mater., 13, 1 (2013)

[13] Macwan DP, Dave PN, Chaturvedi S, J. Mater. Sci., 46(11), 3669 (2011)

[14] Suttiponparnit K, Jiang J, Sahu M, Suvachittanont S, Charinpanitkul T, Biswas P, Nanoscale Res. Lett., 6, 27 (2011)

[15] Joo J, Kwon SG, Yu T, Cho M, Lee J, Yoon J, Hyeon T, J. Phys. Chem. B, 109(32), 15297 (2005)

[16] Yawen W, Lizhi Z, Kejian D, Xinyi C, Zhigang Z, J. Phys. Chem. C, 111, 2709 (2007)

[17] Zhu HY, Gao XP, Lan Y, Song DY, Xi YX, Zhao JC, J. Am. Chem. Soc., 126(27), 8380 (2004)

[18] Grover IS, Singh S, Pal B, Appl. Surf. Sci., 280, 366 (2013)

[19] Liao DL, Liao BQ, J. Photochem. Photobiol. A-Chem., 187, 363 (2007)

[20] Jitputti J, Pavasupree S, Suzuki Y, Yoshikawa S, ECS Trans., 16, 3 (2009)

[21] Kansal SK, Sood S, Umar A, Mehta SK, J. Alloy. Compd., 581, 392 (2013)

[22] Kalpagam S, Kannadasan T, J. Chem. Biol. Phys. Sci., 4, 1936 (2014)

[23] Farbod M, Kajbafvala M, Powder Technol., 239, 434 (2013)

[24] Singla P, Sharma M, Pandey OP, Singh K, Appl. Phys. A-Mater. Sci. Process., 116, 371 (2014)

[25] Mamba G, Mbianda XY, Mishra AK, Mater. Chem. Phys., 149-150, 734 (2015)

[26] Ali Z, Chaudhry MN, Hussain ST, Batool SA, Abbas SM, Ahmad N, Ali N, Niaz NA, Dig. J. Nanomater. Bios., 8, 1271 (2013)

[27] Bavykin DV, Redmond KE, Nias BP, Kulak AN, Walsh FC, Aust. J. Chem., 63, 270 (2010)

[28] Kaur R, Pal B, J. Mol. Catal. A-Chem., 355, 39 (2012)

[29] Kamat PV, J. Phys. Chem. B, 106(32), 7729 (2002)

[30] Gupta N, Pal B, J. Mol. Catal. A-Chem., 371, 48 (2013)

[31] Tsai WT, Chang CY, Lin MC, Chien SF, Sun HF, Hsieh MF, Chemosphere, 45, 51 (2001)

[32] Guillard C, Lachheb H, Houas A, Ksibi M, Elaloui E, Herrmann JM, J. Photochem. Photobiol. A-Chem., 158, 27 (2003)

[33] Wong YC, Szeto YS, Cheung WH, McKay G, Process Biochem., 39, 693 (2004)

[34] Dada AO, Olalekan AP, Olatunya AM, Dada O, IOSR J. Appl. Chem., 3, 38 (2012)

[35] Noguchi T, Fujishima A, Environ. Sci. Technol., 32, 3831 (1998)

[36] Kesselman JM, Lewis NS, Hoffmann MR, Environ. Sci. Technol., 31, 2298 (1997)