화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.34, 105-116, February, 2016
DOI10.1016/j.jiec.2015.10.042  Export Citation
In-situ synthesis of magnetite acrylamide amino-amidoxime nanocomposite adsorbent for highly efficient sorption of U(VI) ions
Zeinab F. Akl1, Shymaa M. El-Saeed2, and Ayman M. Atta2, 3, †
  • 1Egyptian Nuclear and Radiological Regulatory Authority (ENRRA), 3-Ahmed El-zomor Street, El-Zohour Region, P. O. Box 11762, Nasr City, Cairo, Egypt
  • 2Petroleum Application Department, Egyptian Petroleum Research Institute, Nasr City, P.O. Box 11727, Cairo, Egypt
  • 3Surfactants research chair, Chemistry Department, College of Science, King Saud University, PO Box 2455, Riyadh 11451, Saudi Arabia
E-mail:
A new in-situ magnetite nanoparticles inserted into crosslinked poly (acrylamido-amineamidoxime-co-2-acrylamido-2-methylpropane sulfonic acid (AO/AMPS) were prepared and used as novel uranium adsorbents. The prepared composites were applied as adsorbents to remove U(VI) from aqueous solutions that could be separated by a simple magnetic separation method. The removal of U(VI) was evaluated by spectrophotometric method using arsenazo-III as complexing agent. The results showed that, the sorption process strongly depended on pH and the sorption equilibrium can be reached within 150 min. The Langmuir sorption isotherm model correlated well with the uranium sorption equilibrium data for the concentration range of 50.500 mg/L.
Keywords:Amidoxime;Uranyl;Recovery;Magnetite;Nanoparticles
  1. Anirudhan TS, Radhakrishnan PG, J. Environ. Radioact., 100, 250 (2009)
  2. Hazera O, Kartal S, Talanta, 82, 1974 (2010)
  3. Li WP, Han XY, Wang XY, Wang YQ, Wang WX, Xu H, Tan TS, Wu WS, Zhang HX, Chem. Eng. J., 279, 735 (2015)
  4. Zhao YS, Liu CX, Feng M, Chen Z, Li SQ, Tian G, Wang L, Huang JB, Li SJ, J. Hazard. Mater., 176(1-3), 119 (2010)
  5. Buszewski B, Szultka M, Crit. Rev. Anal. Chem., 42, 198 (2012)
  6. Sun YB, Yang ST, Sheng GD, Guo ZQ, Tan XL, Xu JZ, Wang XK, Sep. Purif. Technol., 83, 196 (2011)
  7. Shao DD, Jiang ZQ, Wang XK, Li JX, Meng YD, J. Phys. Chem. B, 113(4), 860 (2009)
  8. Warner CL, Addleman RS, Cinson AD, Droubay TC, Engelhard MH, Nash MA, Warner MG, ChemSusChem, 3, 749 (2010)
  9. Maity D, Agrawal DC, J. Magn. Magn. Mater., 308, 16 (2007)
  10. Ren XM, Wang SW, Yang ST, Li JX, J. Radioanal. Nucl. Chem., 283, 253 (2010)
  11. Li JX, Guo ZQ, Zhang SW, Wang XK, Chem. Eng. J., 172(2-3), 892 (2011)
  12. Zhao GX, Wen T, Yang X, Yang SB, Liao JL, Hu J, Shao DD, Wang XK, J. Chem. Soc.-Dalton Trans., 41, 6182 (2012)
  13. Zong PF, Wang SF, Zhao YL, Wang H, Pan H, He CH, Chem. Eng. J., 220, 45 (2013)
  14. Yetimoglu EK, Kahraman MV, Ercan O, Akdemir ZS, Apohan NK, React. Funct. Polym., 67(5), 451 (2007)
  15. Lee WF, Yuan WY, J. Appl. Polym. Sci., 77(8), 1760 (2000)
  16. Gibon CM, Norvez S, Iiopoulos I, Goldbach JT, Eur. Polym. J., 44, 1843 (2008)
  17. Coskun R, Soykan C, Delibas A, Eur. Polym. J., 42, 625 (2006)
  18. Rivas BL, Maureira A, Geckeler KE, J. Appl. Polym. Sci., 101(1), 180 (2006)
  19. Atta AM, Abd El Wahab ZH, El Shafey ZA, Zidan WI, Akl ZF, J. Dispersion Sci. Technol., 31, 1601 (2010)
  20. Kundakcı S, Uzum OB, Karadag E, Polym. Compos., 32, 994 (2011)
  21. Atta AM, Abd El Wahab ZH, El Shafey ZA, Zidan WI, Akl ZF, J. Dispersion Sci. Technol., 31, 1415 (2010)
  22. Abney CW, Liu SB, Lin WB, J. Phys. Chem. A, 117(45), 11558 (2013)
  23. Xu C, Wang J, Yang T, Chen X, Liu X, Ding X, Carbohydr. Polym., 121, 79 (2015)
  24. Zhao YG, Li JX, Zhao LP, Zhang SW, Huang YS, Wu XL, Wang XK, Chem. Eng. J., 235, 275 (2014)
  25. Wang CZ, Lan JH, Wu QY, Luo Q, Zhao YL, Wang XK, Chai ZF, Shi WQ, Inorg. Chem., 53(18), 9466 (2014)
  26. Zhou L, Xu M, Wei G, Li L, Chubik MV, Chubik MP, Gromov AA, Han W, J. Mater. Sci. -Mater. Electron., 26, 2742 (2015)
  27. Golmohammadi H, Rashidi A, Safdari SJ, Ch&ChT, 6, 245 (2012)
  28. El-Mahdy GA, Atta AM, Al-Lohedan HA, J. Taiwan Inst. Chem. E, 45, 1947 (2014)
  29. Atta AM, Akl ZF, Mater. Chem. Phys., 163, 253 (2015)
  30. El-Mahdy GA, Atta AM, Al-Lohedan HA, Molecules, 19, 1713 (2014)
  31. Atta AM, El-Mahdy GA, Al-Lohedan HA, El-Saeed AM, Molecules, 20, 1244 (2015)
  32. Atta AM, Al-Lohedan HA, Al-Hussain SA, Int. J. Mol. Sci., 16, 6911 (2015)
  33. Atta AM, Ismail HS, Mohamed HM, Mohamed ZM, J. Appl. Polym. Sci., 122(2), 999 (2011)
  34. Akl MA, Atta AM, Yousef AM, Alaa MI, Polym. Int., 62, 1667 (2013)
  35. Dubois LH, Zegarski BR, Nuzzo RG, Langmuir, 2, 412 (1986)
  36. Atta AM, Abdel-Rahman AA, Hamza MF, El Aassy IE, Ahmed FY, J. Dispersion Sci. Technol., 33, 490 (2012)
  37. Yu WW, Du M, Ye WJ, Lv WY, Zheng Q, Polymer, 55(10), 2455 (2014)
  38. Ding P, Zhang J, Song N, Tang S, Liu Y, Shi L, Compos. Pt. A-Appl. Sci. Manuf., 69, 186 (2015)
  39. Madras G, McCoy BJ, J. Chem. Phys., 115(14), 6699 (2001)
  40. Mahfouz MG, Galhoum AA, Gomaa NA, Abdel-Rehem SS, Atia AA, Vincent T, Guibal E, Chem. Eng. J., 262, 198 (2015)
  41. Guibal E, Roulph C, Cloirec PL, Water Res., 26, 1139 (1992)
  42. Kim BC, Lee J, Um W, Kim J, Joo J, Lee JH, Kwak JH, Kim JH, Lee C, Lee H, Addleman RS, Hyeon T, Gu MB, Kim J, J. Hazard. Mater., 192(3), 1140 (2011)