To degrade organic pollutants in water with hydrogen peroxide (H2O2) under visible light (lambda >= 420 nm), a novel water-insoluble iron Schiff base complex, iron(III)-bis-salicylaldehyde-o-aminophenol (Fe-SAP), was prepared and characterized using NMR, MS, IR, and UV-Vis spectroscopy. Rhodamine B (RhB) and salicylic acid were used as probes to characterize the photocatalytic system. High catalytic activity of Fe-SAP was observed over a wide range of pH values from 3 to 9. Scavenging studies of reactive oxygen species (ROS) and ESR experiments indicate that the primary ROS from photocatalytic conversion of H2O2 is O-1(2), rather than center dot OH. To date, there have been few reports on the generation of O-1(2) by iron organic complexes for the oxidative decomposition of organics. The catalyst stability and reusability are good, most likely because the water-insoluble Fe-SAP is able to reduce the damage to its organic ligands by center dot OH. Given these favorable characteristics, Fe-SAP exhibits excellent potential for practical application in removing refractory organic pollutants and pollutants of emerging concern from water and wastewater. (C) 2015 Elsevier B.V. All rights reserved.