화학공학소재연구정보센터
Journal of Loss Prevention in The Process Industries, Vol.11, No.6, 423-430, 1998
Reaction zone structures and propagation mechanisms of flames in stearic acid particle clouds
Reaction zone structures and propagation mechanisms of two representative flames established in stearic acid (CH3(CH2)(16)CO2H) particle clouds have been investigated. The reacting zone structure was examined by using a micro-electrostatic probe and a highspeed schlieren system. A distinct difference was observed in the ion current fluctuations recorded across the two representative flames propagating through the clouds of the same total mass density of particles and different mass densities of the particles smaller than 60 mu m in diameter. When the mass density of smaller particles was high, a single peak was recorded in the ion current fluctuation. On the other hand, when the mass density of smaller particles was low, multi-peaks of various heights and widths were recorded. In the former case, the single peak was considered to be attributable to a unitary and a relatively thin flame started burning in vapor generated by the evaporation of smaller particles in the preheat zone. The flame propagation mechanism in this case was inferred to be similar to that of a usual hydrocarbon-air premixed flame, although the reaction zone thickness is much larger than that of the premixed flame. In the latter case, the multi peaks of various shapes were considered to be attributable to strong combustion at blue spots far behind the schlieren front. The flame propagation in this case was inferred to be supported by the heat release due to combustion at the blue spots.