Applied Surface Science, Vol.336, 48-52, 2015
Resonant photothermal laser processing of hybrid gold/titania nanoparticle films
Photothermal processing of thin anatase TiO2 and hybrid Au/anatase TiO2 nanoparticle films on glass supports is investigated using continuous-wave microfocused lasers at lambda = 355 nm and lambda = 532 nm. UV/Vis spectroscopy, Raman spectroscopy, optical microscopy, atomic force microscopy and scanning electron microscopy are used for characterization. Processing of TiO2 nanoparticle films is feasible at lambda = 355 nm only. In contrast, the addition of Au nanoparticles enhances the overall absorbance of the material in the visible range and enables processing at both wavelengths, i.e. at lambda = 355 nm and lambda = 532 nm. Generally, laser heating induces a transition from anatase to rutile. The modification degree increases with increasing laser power and laser irradiation time. Resonant laser processing of hybrid Au/TiO2-mesoporous films provide promising perspectives in various applications, e.g. in photovoltaics, where embedded nanoparticulate Au could be exploited to enhance light trapping. (C) 2014 Published by Elsevier B.V.
Keywords:Titanium dioxide;Gold nanoparticle;Plasmon resonance;Resonant photothermal processing;Laser sintering;Mesoporous electrodes