Applied Surface Science, Vol.355, 477-483, 2015
Spatially resolved nanostructural transformation in graphite under femtosecond laser irradiation
A polycrystalline graphite target was irradiated using infrared (800 nm) femtosecond (120 fs) laser pulses of different energies. Increase of sp(3) bonds percentage and possible diamond crystal formation were investigated 'in-depth' and on the irradiated surfaces. Synchrotron X-ray diffraction pattern have shown the presence of a diamond peak in one of the irradiated zones while X-ray photoelectron spectroscopy investigations have shown an increasing tendency of the sp(3) percent in the low power irradiated areas and similarly 'in the depth' of the higher power irradiated zones. Multiple wavelength Micro-Raman investigations have confirmed this trend along with an 'in-depth' (but not on the surface) increase of the crystallite size. Based on the wavelength dependent photon absorption into graphite, the observed effects are correlated with high density photon per atom and attributed to the melting and recrystallization processes taking place tens of nanometers below the target surface. (c) 2015 Elsevier B.V. All rights reserved.
Keywords:Graphite-diamond transition;sp2-sp3 transition;Fs laser irradiation;Laser-induced surface modifications