Applied Surface Science, Vol.355, 800-804, 2015
Integration of plasmonic Ag nanoparticles as a back reflector in ultra-thin Cu(In,Ga)Se-2 solar cells
Integration of plasmonic Ag nanoparticles as a back reflector in ultra-thin Cu(In,Ga)Se-2 (CIGSe) solar cells is investigated. X-ray photoelectron spectroscopy results show that Ag nanoparticles underneath a Sn:In2O3 back contact could not be thermally passivated even at a low substrate temperature of 440 degrees C during CIGSe deposition. It is shown that a 50 nm thick Al2O3 film prepared by atomic layer deposition is able to block the diffusion of Ag, clearing the thermal obstacle in utilizing Ag nanoparticles as a back reflector in ultra-thin CIGSe solar cells. Via 3-D finite element optical simulation, it is proved that the Ag nanoparticles show the potential to contribute the effective absorption in CIGSe solar cells. (C) 2015 Elsevier B.V. All rights reserved.
Keywords:Ultra-thin Cu(ln,Ga)Se-2 solar cells;Ag nanoparticles;Thermal stability;Al2O3 film;Atomic layer deposition