화학공학소재연구정보센터
Journal of Materials Science, Vol.29, No.21, 5693-5698, 1994
Oxidation Protection of Porous Reaction-Bonded Silicon-Nitride
Oxidation kinetics of both as-fabricated and coated reaction-bonded silicon nitride (RBSN) were studied at 900 and 1000 degrees C with thermogravimetry. Uncoated RBSN exhibited internal oxidation and parabolic kinetics. An amorphous Si-C-O coating provided the greatest degree of protection to oxygen, with a small linear weight loss observed. Linear weight gains were measured on samples with an amorphous Si-N-C coating. Chemically vapour deposited (CVD) Si3N4 coated RBSN exhibited parabolic kinetics, and the coating cracked severely. A continuous-SiC-fibre-reinforced RBSN composite was also coated with the Si-C-O material, but no substantial oxidation protection was observed.