Applied Chemistry, Vol.1, No.1, 242-245, May, 1997
CO2와 Epoxide의 반응에 의해 합성된 Cyclic Carbonate의 응용 I. Hydroxy-terminated Linear Polycarbonate의 합성
Application of Cyclic Carbonate Synthesized from Reaction with Epoxide and CO2 I. Synthesis of Hydroxy-terminated Linear Polycarbonate
In this paper, the synthesis of hydroxy-terminated linear polycarbonate was studied to understand the effect of mole ratio of initiators, kind of catalyst and structure of initiator. Mixed catalyst of Potassium tert-butoxide and 18-crown-6 showed higher yield than potassium tert-butoxide alone. We also investigated the characteristics of hydroxy-terminated linear polycarbonate by DSC, TGA, GPC.