Multifunctional hyperbranched polyamine modified graphene oxide (HPA-GO) was successfully prepared and characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), zeta potential and scanning electron microscope (SEM) analyses. HPA-GO exhibited excellent adsorption performance for the removal of a heavy metal (Pb(II)) and a dye (methylene blue (MB)). The equilibrium adsorption capacity was 819.7 mg g(-1) for Pb(II) and 740.7 mg g(-1) for MB under the optimal conditions. The pseudo-second order equation and the Langmuir model exhibited good correlation with the adsorption kinetic and isotherm data, respectively, for these two pollutants. The thermodynamic results (Delta G < 0, Delta H > 0, Delta S > 0) implied that the adsorption process of Pb(II) and MB was feasible, endothermic and spontaneous in nature. A possible adsorption mechanism has been proposed where chelation and electrostatic attraction dominated the adsorption of Pb(II) and pi-pi stacking interactions and electrostatic attraction dominated the adsorption of MB. In addition, the excellent reproducibility endowed HPA-GO with the potential for application in water treatment. (C) 2015 Elsevier B.V. All rights reserved.