화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.35, 167-176, March, 2016
DOI10.1016/j.jiec.2015.12.028  Export Citation
Sonochemical synthesis of holmium doped zinc oxide nanoparticles: Characterization, sonocatalysis of reactive orange 29 and kinetic study
Alireza Khataee†, Shabnam Saadi, Behrouz Vahid1, and Sang Woo Joo2, †
  • Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, 51666-16471 Tabriz, Iran
  • 1Department of Chemical Engineering, Tabriz Branch, Islamic Azad University, 51579-44533 Tabriz, Iran
  • 2School of Mechanical Engineering, Yeungnam University, 712-749 Gyeongsan, South Korea
E-mail:,
The sonochemically synthesized Ho-doped ZnO nanoparticles were characterized by XRD, SEM, TEM, and XPS techniques. The sonocatalytic degradation of Reactive Orange 29 (RO29) was greater than that with sonolysis alone. DE% declines with the addition of chloride, carbonate, sulfate, and tert-butanol as radical scavengers. Addition of potassium periodate, peroxydisulfate, and hydrogen peroxide as enhancers improves DE%. The results demonstrate proper reusability of the doped sonocatalyst. Degradation intermediates were identified by gas chromatography-mass spectrometry (GC-MS). Using nonlinear regression analysis, an empirical kinetic model was developed to predict the pseudo-first- order constants (kapp) as a function of the operational parameters.
Keywords:Sonication;Sonocatalyst;Nanocatalyst;Reactive Orange 29;Kinetic modeling
  1. Prado J, Arantegui J, Chamarro E, Esplugas S, Ozone Sci. Eng., 16, 235 (1994)
  2. Wang J, Jiang Z, Zhang Z, Xie Y, Wang X, Xing Z, Xu R, Zhang X, Ultrason. Sonochem., 15, 768 (2008)
  3. Suslick KS, Hammerton DA, Cline RE, J. Am. Chem. Soc., 108, 5641 (1986)
  4. Shimizu N, Ogino C, Dadjour MF, Murata T, Ultrason. Sonochem., 14, 184 (2007)
  5. Anju S, Jyothi K, Joseph SYS, Yesodharan E, Res. J. Recent Sci., 2277, 2502 (2012)
  6. Pera-Titus M, Garcia-Molina V, Banos MA, Gimenez J, Esplugas S, Appl. Catal. B: Environ., 47(4), 219 (2004)
  7. Gogate PR, Pandit AB, Adv. Environ. Res., 8, 501 (2004)
  8. Ghows N, Entezari M, Ultrason. Sonochem., 20, 386 (2013)
  9. Song L, Chen C, Zhang S, Wei Q, Ultrason. Sonochem., 18, 1057 (2011)
  10. Wang J, Jiang Z, Zhang ZH, Xie YP, Lv YH, Li J, Deng YQ, Zhang XD, Sep. Purif. Technol., 67(1), 38 (2009)
  11. Soltani RDC, Rezaee A, Khataee A, Ind. Eng. Chem. Res., 52(39), 14133 (2013)
  12. Khataee A, Karimi A, Arefi-Oskoui S, Soltani RDC, Hanifehpour Y, Soltani B, Joo SW, Ultrason. Sonochem., 22, 371 (2015)
  13. Suwanboon S, Amornpitoksuk P, Muensit N, Ceram. Int., 37, 2247 (2011)
  14. Phuruangrat A, Thongtem T, Thongtem S, Mater. Lett., 63, 1224 (2009)
  15. Bigdeli F, Morsali A, Mater. Lett., 64, 4 (2010)
  16. Khataee A, Hosseini M, Hanifehpour Y, Safarpour M, Joo S, Res. Chem. Intermed., 40, 495 (2014)
  17. Yayapao O, Thongtem T, Phuruangrat A, Thongtem S, J. Alloy. Compd., 576, 72 (2013)
  18. Aslani A, Bazmandegan-Shamili A, Kaviani K, J. Phys. Condens. Matter, 405, 3972 (2010)
  19. Wahab R, Ansari SG, Kim YS, Seo HK, Shin HS, Appl. Surf. Sci., 253(18), 7622 (2007)
  20. Khataee A, Vahid B, Behjati B, Safarpour M, Joo SW, Chem. Eng. Res. Des., 92(2), 362 (2014)
  21. Khataee AR, Fathinia M, Zarei M, Izadkhah B, Joo SW, J. Ind. Eng. Chem., 20(4), 1852 (2014)
  22. Ghows N, Entezari MH, J. Hazard. Mater., 195, 132 (2011)
  23. Gandhi V, Ganesan R, Syedahamed HHA, Thaiyan M, J. Phys. Chem. C, 118, 9715 (2014)
  24. Bae SY, Seo HW, Park JH, J. Phys. Chem. B, 108(17), 5206 (2004)
  25. Chen M, Wang X, Yu YH, Pei ZL, Bai XD, Sun C, Huang RF, Wen LS, Appl. Surf. Sci., 158(1-2), 134 (2000)
  26. Zhou WY, He YC, Chem. Eng. J., 179, 412 (2012)
  27. Farhadi S, Pourzare K, Sadeghinejad S, Polyhedron, 67, 104 (2014)
  28. Behnajady MA, Modirshahla N, Shokri M, Vahid B, Ultrason. Sonochem., 15, 1009 (2008)
  29. Manousaki E, Psillakis E, Kalogerakis N, Mantzavinos D, Water Res., 38, 3751 (2004)
  30. Anju SG, Yesodharan S, Yesodharan EP, Chem. Eng. J., 189, 84 (2012)
  31. Khataee A, Sheydaei M, Hassani A, Taseidifar M, Karaca S, Ultrason. Sonochem., 22, 404 (2015)
  32. Salavati H, Tavakkoli N, Hosseinpoor M, Ultrason. Sonochem., 19, 546 (2012)
  33. Selli E, Phys. Chem. Chem. Phys., 4, 6123 (2002)
  34. Yayapao O, Thongtem T, Phuruangrat A, Thongtem S, Mater. Lett., 90, 83 (2013)
  35. Sin JC, Lam SM, Lee KT, Mohamed AR, Ceram. Int., 39, 5833 (2013)
  36. Zhai Y, Li Y, Wang J, Wang J, Yin LN, Kong YM, Han GX, Fan P, J. Mol. Catal. A-Chem., 366, 282 (2013)
  37. Khataee A, Soltani RDC, Hanifehpour Y, Safarpour M, Ranjbar HG, Joo SW, Ind. Eng. Chem. Res., 53(5), 1924 (2014)
  38. Khataee A, Khataee A, Fathinia M, Hanifehpour Y, Joo SW, Ind. Eng. Chem. Res., 52, 13357 (2013)
  39. Khatamian M, Khandar AA, Divband B, Haghighi M, Ebrahimiasl S, J. Mol. Catal. A-Chem., 365, 120 (2012)
  40. Ertugay N, Acar FN, Appl. Surf. Sci., 318, 121 (2014)
  41. Pang YL, Abdullah AZ, Appl. Catal. B: Environ., 129, 473 (2013)
  42. Pang YL, Abdullah AZ, Bhatia S, Desalination, 277(1-3), 1 (2011)
  43. Wang J, Jiang Z, Zhang L, Kang P, Xie Y, Lv Y, Xu R, Zhang X, Ultrason. Sonochem., 16, 225 (2009)
  44. Golash N, Gogate PR, Ultrason. Sonochem., 19, 1051 (2012)
  45. Hou LW, Zhang H, Wang LG, Chen L, Chem. Eng. J., 229, 577 (2013)
  46. Frontistis Z, Mantzavinos D, Ultrason. Sonochem., 19, 77 (2012)
  47. Gozmen B, Environ. Prog. Sust. Energy, 31, 296 (2012)
  48. Ervens B, Gligorovski S, Herrmann H, Phys. Chem. Chem. Phys., 5, 1811 (2003)
  49. Chen CY, Water Air Soil Pollut., 202, 335 (2009)
  50. Khataee AR, Kasiri MB, J. Mol. Catal. A-Chem., 331(1-2), 86 (2010)
  51. Marandi R, Olya ME, Vahid B, Khosravi M, Hatami M, Environ. Eng. Sci., 29, 957 (2012)