화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.35, 177-184, March, 2016
DOI10.1016/j.jiec.2015.12.031  Export Citation
Bimetallic Au-Sn/AC catalysts for acetylene hydrochlorination
Yanzhao Dong, Haiyang Zhang, Wei Li1, Mengxia Sun1, Cuili Guo1, and Jinli Zhang†
  • Key Laboratory of Systems Bioengineering MOE, Tianjin University, Tianjin 300072, PR China
  • 1Key Laboratory for Green Chemical Technology MOE, Tianjin University, Tianjin 300072, PR China
E-mail:
A series of Au-Sn/AC catalysts for acetylene hydrochlorination were prepared by an incipient wetness impregnation method and characterized by BET, XPS, TEM, TPR, XRD, ICP-AES and TPD techniques. It is indicated that Au1Sn1/AC catalyst shows the highest activity and stability with the 95% acetylene conversion after 48 h reaction under the conditions of 170 ℃ and an acetylene gas hourly space velocity of 720 h-1. The Sn additive can make the Au species dispersed well and weaken the occurrence of coke deposition, as well as inhibit the reduction of Au3+ to Au0, thereby improving the catalytic activity and stability.
Keywords:Acetylene hydrochlorination;Au-Sn catalyst;Coking deposition
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