화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.35, 347-356, March, 2016
DOI10.1016/j.jiec.2016.01.015  Export Citation
Adsorptive Li+ mining from liquid resources by H2TiO3:Equilibrium, kinetics, thermodynamics, and mechanisms
Chosel P. Lawagon, Grace M. Nisola, Junyoung Mun1, Artur Tron1, Rey Eliseo C. Torrejos, Jeong Gil Seo, Hern Kim, and Wook-Jin Chung†
  • Energy and Environment Fusion Technology Center (E2FTC), Department of Energy Science and Technology (DEST), Myongji University, Myongjiro-116, Cheoingu, Yongin City, Gyeonggi Province (17058), Republic of Korea
  • 1Department of Energy and Chemical Engineering, Incheon National University, 12-1, Songdo-dong, Yeonsu-gu, Incheon 406-840, Republic of Korea
E-mail:
Metatitanic acid (H2TiO3) is an emerging lithium ion sieve (LIS) that can potentially replace the well-known manganese-based LIS. Systematic adsorption studies on the effects of solution pH, solid/liquid ratio, temperature, and feed concentration were conducted. H+ accumulation critically limited the Li+ capacity (qe), but was circumvented under optimal conditions. Li+ adsorption was Langmuir-type and followed pseudo-second-order rate model; thermodynamic parameters reveal its feasibility, spontanei-ty, and endothermicity. H2TiO3 was highly stable and reusable; its highest qe (94.5 mg g-1) is superior over other known LIS. Li+ was effectively recovered from seawater, demonstrating its high industrial potential for aqueous Li+ mining.
Keywords:Adsorption;Metatitanic acid;Seawater;Lithium recovery;Ion sieve
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