Journal of Materials Science, Vol.30, No.9, 2296-2298, 1995
Ab-Initio Self-Consistent Theory of Ionic-Diffusion in Superionic Conductors with an Internal Interface
The kinetic equation of the hopping diffusion in a one-dimensional chain with an internal interface between a superionic conductor and an intercalate, is presented in a new form, which explicitly takes into account the effect of Coulomb correlations. Numerical results are presented for material parameters corresponding to the system : ternary borate glass-indium selenide, which is often used in solid microbatteries.
Keywords:HOPPING DIFFUSION