화학공학소재연구정보센터
Electrochimica Acta, Vol.178, 18-24, 2015
Efficient dye-sensitized solar cells from curved silicate microsheet caged TiO2 photoanodes. An avenue of enhancing light harvesting
Enhancement of light harvesting has been a persistent objective for elevating dye excitation and therefore power conversion efficiency of dye-sensitized solar cells (DSSCs). Here we launch a strategy of markedly enhancing light harvesting by caging TiO2 nanoparticles with curved silica microsheets. The results show that the strategy is versatile in suppressing the recombination reaction of electrons with I-3(-) species in liquid electrolyte. Due to the superior reflective behaviors of curved silica microsheets, an optimal efficiency of 9.22% is recorded under simulated air mass 1.5 global sunlight on the DSSC in comparison with 6.51% and 7.51% from pristine TiO2 and planar silicate microsheet incorporated TiO2 photoanode based solar cells, respectively. This strategy is also believed to be applicable to other solar cells such as perovskite solar cells and quantum dot-sensitized solar cells. (C) 2015 Elsevier Ltd. All rights reserved.