Electrochimica Acta, Vol.156, 70-76, 2015
Graphene and maghemite composites based supercapacitors delivering high volumetric capacitance and extraordinary cycling stability
Metal oxides (like MnO2, Fe2O3, and Co3O4, etc) based supercapacitors have disadvantages, such as low volumetric capacitance for thick-film electrodes, or short cycling life because a Faradaic process involves chemical changes of state of the reactant species. In the present work, we report that supercapacitors based on reduced graphene oxide and maghemite (gamma-Fe2O3) composites (G gamma M) exhibit superior performance. G gamma M electrodes with average electrode thickness up to similar to 60 mu m have a high volumetric capacitance of 230 F cm(-3), together with an outstanding electrode package density of 1.44 g cm(-3). Particularly, the GgM electrodes have excellent cycling performance of similar to 90% capacitance retention over 100,000 galvanostatic charge-discharge cycles or voltage floating at 0.9 V for 300 h. No detectable change in phase and an effective inhibition of gamma-Fe2O3 refinement after cycle-life test are confirmed by X-ray diffraction and transmission electron microscopy. (C) 2015 Elsevier Ltd. All rights reserved.