This study proposes and investigates a novel VCES (Vehicle power and cooling/heating Cogeneration Energy System), including a topping vehicle engine subsystem, and a bottoming waste-heat recovery subsystem which uses the zeotropic working fluid. The various grade exhaust and coolant waste-heat of the topping subsystem are cascade recovered by the bottoming subsystem, and slide-temperature thermal match in waste heat recovery heat exchangers and the condenser is considered also, obtaining power output and cooling/heating capacity. Based on the experimental data from an actual vehicle's energy demands and its waste-heat characteristics, the proposed VCES (vehicle cogeneration energy system) model is built and verified. Using ammonia-water as working fluid of the bottoming subsystem, integrated thermodynamic performances of the VCES are discussed through introducing three variables: an ambient temperature, the vehicle's velocity and the number of seated occupants. The influence of above three variables on the proposed VCES' overall thermodynamic performance is analyzed by comparing it to a conventional VCES, and suitable operation conditions are recommended under cooling and heating conditions. (C) 2015 Elsevier Ltd. All rights reserved.