Toluene reference fuel (TRF) is a kind of surrogate fuel for diesel. Clarifying the combustion mechanism of TRF is a key to understand the combustion of diesel. Alcohols are added into diesel to reduce the soot emission from engines. The formation mechanism of soot precursors, i.e., polyaromatic hydrocarbons (PAHs), in the premixed laminar flames of TRF, methanol-TRF blend, ethanol-TRF blend, and n-butanol-TRF blend were investigated experimentally and theoretically. A partly reduced n-butanol combustion mechanism, including the sub-mechanism of methanol and ethanol, and a partly reduced soot formation mechanism were merged into a partly reduced mechanism of TRF to simulate the combustion of the TRF-alcohol blends. Additions of methanol, ethanol, and n-butanol can reduce the mole fractions of the PAHs in TRF flames at an equivalence ratio of 2.0. The mole fractions of the PAHs in the flames are in the order of n-butanol-TRF < ethanol-TRF < methanol-TRF (

Keywords:Butanol;Ethanol;Methanol;TRF;PAH